{"id":"W3121756348","doi":"10.20944/preprints201703.0158.v1","title":"Triphenylphosphine-(<em>N</em>,<em>N</em>-dimethyldithiocarbamato)-gold(I) Methanol Solvate","year":2017,"lang":"en","type":"preprint","venue":"Preprints.org","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Stantec (Canada); Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Raman spectroscopy; Denticity; Triphenylphosphine; Density functional theory; Single crystal; Chemistry; Crystallography; Ligand (biochemistry); Crystal structure; Materials science; Computational chemistry; Physics; Optics; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001164696,0.000286946,0.0002507133,0.0001463076,0.000234591,0.000221164,0.0004659457,0.0003278911,0.005821527],"category_scores_gemma":[0.0001768743,0.0001957238,0.0001180729,0.0002419102,0.000155831,0.0001893302,0.0002455134,0.0002766452,0.001049868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004798794,"about_ca_system_score_gemma":0.0002698952,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001020493,"about_ca_topic_score_gemma":0.001779199,"domain_scores_codex":[0.9998723,0.00001144178,0.00000627719,0.00004782829,0.0000334024,0.00002871372],"domain_scores_gemma":[0.9999375,0.00001814828,0.00001446838,0.00001077698,0.000009653953,0.000009415187],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001562643,0.00001564017,0.00008989692,0.0001850882,0.0000107544,0.00009602168,0.00003319987,0.0004699744,0.9952478,0.0004707388,0.0003555123,0.002869143],"study_design_scores_gemma":[0.0000255121,0.0001621848,0.0002255405,0.000004471276,0.00001030875,0.00008584628,0.00001789065,0.001131586,0.9950134,0.00007645848,0.003241827,0.000004936684],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.974075,0.000951505,0.01284636,0.0002352546,0.0000611364,0.00009366612,0.0009109223,0.0004883638,0.01033777],"genre_scores_gemma":[0.9831709,0.0005054791,0.00869152,0.00006751456,0.000008829115,0.0000952115,0.0007033488,0.00008790338,0.006669373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005821527,"threshold_uncertainty_score":0.01947492,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05015395519670167,"score_gpt":0.2870488729410535,"score_spread":0.2368949177443518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}