{"id":"W3124848519","doi":"10.1039/d0sc06465c","title":"<i>N</i>-Heterocyclic carbene–carbodiimide (NHC–CDI) betaine adducts: synthesis, characterization, properties, and applications","year":2021,"lang":"en","type":"review","venue":"Chemical Science","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; National Institute of General Medical Sciences; University of British Columbia; National Science Foundation; National Institutes of Health; Newcastle University; University of Minnesota","keywords":"Carbodiimide; Carbene; Betaine; Adduct; Characterization (materials science); Chemistry; Combinatorial chemistry; Polymer chemistry; Organic chemistry; Materials science; Nanotechnology; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001591905,0.0003844526,0.0002650521,0.0008611673,0.0001367665,0.000350673,0.0003016853,0.000384877,0.001683347],"category_scores_gemma":[0.0001405468,0.0001182437,0.0001272414,0.0007750113,0.0001992886,0.0004813278,0.0002087175,0.0007056731,0.001110671],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003596153,"about_ca_system_score_gemma":0.0003935349,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000664987,"about_ca_topic_score_gemma":0.00177942,"domain_scores_codex":[0.9999522,0.000005093745,0.000004532912,0.00001314833,0.00001707178,0.000007988671],"domain_scores_gemma":[0.9999372,0.00002413339,0.00001337466,0.000003286001,0.00001413303,0.000007840078],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000449848,0.00009294127,0.0001911239,0.00911488,0.00002554318,0.000174855,0.00005037752,0.0004276126,0.03431945,0.01130716,0.02414401,0.920107],"study_design_scores_gemma":[0.000003508272,0.000101631,0.0005649081,0.0004936793,0.00002010321,0.0007393915,0.00002294316,0.0001034484,0.00893101,0.00077962,0.9882296,0.00001016556],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.001514136,0.9859099,0.000826032,0.0004594089,0.0005250852,0.00001381697,0.00004411061,0.00002717529,0.01068025],"genre_scores_gemma":[0.009186042,0.9798431,0.0009011198,0.0005488414,0.0004071675,0.00002259865,0.00009330353,0.000006681282,0.008991257],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.001683347,"threshold_uncertainty_score":0.005631387,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03236882287474112,"score_gpt":0.2652020568032836,"score_spread":0.2328332339285425,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}