{"id":"W3125729937","doi":"10.1002/celc.202001531","title":"Optimizing the Electrochemiluminescence of Readily Accessible Pyrido[1,2‐α]pyrimidines through “Green” Substituent Regulation","year":2021,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Tianjin University; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Electrochemiluminescence; Chemistry; Photochemistry; Oxidizing agent; Monomer; Substituent; Excited state; Pyrimidine; Photoluminescence; Radical; Combinatorial chemistry; Organic chemistry; Stereochemistry; Materials science; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001458011,0.0003013923,0.0001373083,0.0000980187,0.00007726751,0.000241599,0.0002594265,0.0002634741,0.0004971036],"category_scores_gemma":[0.0001943376,0.0001348747,0.000140687,0.0001090452,0.0001304005,0.0002730945,0.0001322889,0.0003147289,0.0001722106],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002034163,"about_ca_system_score_gemma":0.00009073704,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000216668,"about_ca_topic_score_gemma":0.0004965426,"domain_scores_codex":[0.9998897,0.00001824056,0.000008189922,0.00003090496,0.0000305698,0.00002243045],"domain_scores_gemma":[0.9999412,0.00001105,0.0000251351,0.000004766009,0.00001117354,0.000006579118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001143368,0.000004840919,0.00003474918,0.00002304248,0.000001340452,0.00001576872,0.000006253655,0.00007316359,0.999231,0.00005538638,0.00001128128,0.0005317303],"study_design_scores_gemma":[0.000004493581,0.00005689703,0.000301753,0.000001567746,0.000002549459,0.00003517943,0.000004463964,0.0006627957,0.9983,0.00001314345,0.0006150796,0.000002061217],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9852542,0.001122305,0.0115752,0.00006801408,0.00002356492,0.00005229407,0.0001209573,0.00009703436,0.001686352],"genre_scores_gemma":[0.991239,0.0004698516,0.007462371,0.00002688869,0.00000496658,0.00002484815,0.00008763082,0.00001251615,0.0006719343],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004971036,"threshold_uncertainty_score":0.00166297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01333083593493661,"score_gpt":0.2722365059904188,"score_spread":0.2589056700554822,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}