{"id":"W3125729937","doi":"10.1002/celc.202001531","title":"Optimizing the Electrochemiluminescence of Readily Accessible Pyrido[1,2‐α]pyrimidines through “Green” Substituent Regulation","year":2021,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Tianjin University; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Electrochemiluminescence; Chemistry; Photochemistry; Oxidizing agent; Monomer; Substituent; Excited state; Pyrimidine; Photoluminescence; Radical; Combinatorial chemistry; Organic chemistry; Stereochemistry; Materials science; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001698451,0.0002382699,0.0002635699,0.00003078021,0.0001447284,0.0000289859,0.0003084766,0.0001763695,0.000008372827],"category_scores_gemma":[0.0001665736,0.0001856904,0.0001926201,0.0005310124,0.0001731601,0.00001481886,0.0001317366,0.0001523871,0.000001210388],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003568987,"about_ca_system_score_gemma":0.000156789,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001561608,"about_ca_topic_score_gemma":0.00003196188,"domain_scores_codex":[0.9984735,0.00004225606,0.0003543358,0.0005032799,0.0002311558,0.0003954939],"domain_scores_gemma":[0.9985642,0.00002325688,0.0002410154,0.0006679748,0.0004555648,0.00004798113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006276475,0.00005942494,0.0001624512,0.00003427723,0.00007639667,0.000002175769,0.00005169762,0.000008094793,0.9975858,0.000163617,0.0009599092,0.0008333586],"study_design_scores_gemma":[0.0001927261,0.00007618526,0.0001293671,0.00003572217,0.00006870375,0.00004139677,0.00008917373,0.0000853494,0.9932324,0.000468315,0.005353373,0.0002272411],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9709277,0.004994652,0.01877132,0.001212986,0.00006239052,0.0002061286,0.000006319458,0.00009021423,0.003728291],"genre_scores_gemma":[0.9845226,0.001075535,0.01262432,0.0003554481,0.0002586426,0.00001677635,0.0002227318,0.00002758805,0.0008963007],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01359496,"threshold_uncertainty_score":0.7572236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01333083593493661,"score_gpt":0.2722365059904188,"score_spread":0.2589056700554822,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}