{"id":"W3133289580","doi":"10.1002/aoc.6198","title":"Immobilizing palladium on melamine‐functionalized magnetic nanoparticles: An efficient and reusable phosphine‐free catalyst for Mizoroki–Heck reaction","year":2021,"lang":"en","type":"article","venue":"Applied Organometallic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Sunnybrook Research Institute","keywords":"Chemistry; Catalysis; Melamine; Thermogravimetric analysis; Palladium; X-ray photoelectron spectroscopy; Heck reaction; Fourier transform infrared spectroscopy; Coupling reaction; Nuclear chemistry; Nanoparticle; Magnetic nanoparticles; Cyanuric chloride; Heterogeneous catalysis; Polymer chemistry; Inorganic chemistry; Chemical engineering; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002585673,0.0004888939,0.0005231912,0.0000475038,0.0004203098,0.0002157305,0.0003530035,0.0003078218,0.002628359],"category_scores_gemma":[0.0004179673,0.0005440323,0.0001800153,0.000438893,0.0002320427,0.00009482454,0.00021152,0.0003580509,0.00005305911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004115505,"about_ca_system_score_gemma":0.0002235608,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005146701,"about_ca_topic_score_gemma":0.00002041878,"domain_scores_codex":[0.9970542,0.000001723361,0.0006360538,0.001250374,0.0004526794,0.0006049238],"domain_scores_gemma":[0.9972587,0.0003458154,0.0002394817,0.001620795,0.0002033482,0.0003318354],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002837377,0.0006310164,0.00003516305,0.0004324519,0.0001140075,0.00001260047,0.0001473945,0.0002641341,0.9967519,0.0003065654,0.0001599622,0.0008610894],"study_design_scores_gemma":[0.002950228,0.00003558042,0.0001444516,0.00005232917,0.0002753326,0.0001272376,0.001019275,0.0008493806,0.9866183,0.0003858235,0.006971499,0.0005705425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937563,0.0006410895,0.00003670749,0.0002033097,0.0001647929,0.0002555219,0.0001717656,0.0002953727,0.004475129],"genre_scores_gemma":[0.9909424,0.00005697713,0.0003823318,0.00007533863,0.0003820611,0.0003251818,0.001299417,0.0001320743,0.006404236],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01013356,"threshold_uncertainty_score":0.9997011,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01164725642081277,"score_gpt":0.2314424763748735,"score_spread":0.2197952199540607,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}