{"id":"W3134503256","doi":"10.21203/rs.3.rs-138056/v1","title":"Substituent-induced electronic localization of nickel phthalocyanine with enhanced electrocatalytic CO2 reduction","year":2021,"lang":"en","type":"preprint","venue":"","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Canadian Light Source (Canada)","funders":"Shenzhen Science and Technology Innovation Program; National Natural Science Foundation of China","keywords":"Nickel; Phthalocyanine; Substituent; Reduction (mathematics); Chemistry; Photochemistry; Materials science; Stereochemistry; Organic chemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006595767,0.0002937305,0.0001548419,0.00007129926,0.0001234113,0.0001854318,0.0003224091,0.0001918973,0.0009657297],"category_scores_gemma":[0.000154866,0.0001183804,0.0001247494,0.0001223779,0.0002020173,0.0002941209,0.0002969588,0.0002243975,0.0001966494],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002037395,"about_ca_system_score_gemma":0.0001080965,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002304705,"about_ca_topic_score_gemma":0.0003723314,"domain_scores_codex":[0.9999486,0.000005621699,0.000003542134,0.00001466009,0.00001374211,0.00001380158],"domain_scores_gemma":[0.9999508,0.000009062841,0.00001603929,0.000008170957,0.000009473984,0.000006531593],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008445323,0.00002802092,0.0002927531,0.0001422483,0.000006848339,0.0001009928,0.00003146342,0.0005182105,0.9931011,0.0006223709,0.0001984688,0.004873059],"study_design_scores_gemma":[0.00001000654,0.00008651991,0.0005826362,0.000002096552,0.000006294952,0.00006916103,0.000009488946,0.002937274,0.9950475,0.00004070364,0.001203326,0.000005128073],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895554,0.0005317847,0.005546652,0.0001274417,0.0000367796,0.00001961167,0.00006463275,0.0001662402,0.003951434],"genre_scores_gemma":[0.9962724,0.0001910949,0.00259674,0.00003716285,0.000008938898,0.00001684705,0.00004798157,0.00002157209,0.0008072384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009657297,"threshold_uncertainty_score":0.003230751,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01122710806522309,"score_gpt":0.2458650517976098,"score_spread":0.2346379437323867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}