{"id":"W3137322287","doi":"10.1016/j.matt.2021.02.017","title":"Organic molecules with inverted gaps between first excited singlet and triplet states and appreciable fluorescence rates","year":2021,"lang":"en","type":"article","venue":"Matter","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":164,"is_retracted":false,"has_abstract":false,"ca_institutions":"Vector Institute; Canadian Institute for Advanced Research; University of Toronto","funders":"Natural Resources Canada; Horizon 2020; Defense Advanced Research Projects Agency; H2020 Marie Skłodowska-Curie Actions; University of Toronto; Centro de Investigaciones Sociológicas; Government of Ontario; Canada Foundation for Innovation; Ontario Research Foundation","keywords":"Intersystem crossing; Excited state; Singlet state; Singlet fission; Photon upconversion; Triplet state; OLED; Fluorescence; Photochemistry; Materials science; Chemistry; Optoelectronics; Atomic physics; Luminescence; Physics; Nanotechnology; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003114737,0.000292218,0.0002230137,0.0002521259,0.0002186791,0.0004615203,0.0003772189,0.0005934635,0.001956158],"category_scores_gemma":[0.0005781907,0.0001918485,0.0001121458,0.0002628025,0.0004379264,0.000555455,0.0003082625,0.000817646,0.0003869222],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003081473,"about_ca_system_score_gemma":0.0002072547,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001288952,"about_ca_topic_score_gemma":0.0002588227,"domain_scores_codex":[0.9998941,0.00001797443,0.00000392322,0.0000218209,0.00002727074,0.00003484347],"domain_scores_gemma":[0.9996859,0.0001623111,0.00005037908,0.00003597115,0.00002923937,0.0000362943],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003671632,0.00007042436,0.0003436643,0.000173698,0.000006758305,0.0000910031,0.0000740013,0.000494352,0.9737109,0.01733376,0.0002165156,0.007117789],"study_design_scores_gemma":[0.00004113418,0.0002061257,0.0007147367,0.000006933321,0.00001244332,0.0002172541,0.00003129568,0.002084614,0.9906161,0.001841954,0.004217685,0.000009805245],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9715385,0.00182284,0.01228733,0.0002491779,0.00009625905,0.00004767896,0.0001519506,0.0002043869,0.01360199],"genre_scores_gemma":[0.9898704,0.0004655306,0.006054511,0.00009588315,0.00002152232,0.00003963986,0.0001516647,0.00003242972,0.003268512],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001956158,"threshold_uncertainty_score":0.006543994,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007278424454488733,"score_gpt":0.1997679541155706,"score_spread":0.1924895296610819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}