{"id":"W3137322287","doi":"10.1016/j.matt.2021.02.017","title":"Organic molecules with inverted gaps between first excited singlet and triplet states and appreciable fluorescence rates","year":2021,"lang":"en","type":"article","venue":"Matter","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":164,"is_retracted":false,"has_abstract":false,"ca_institutions":"Vector Institute; Canadian Institute for Advanced Research; University of Toronto","funders":"Natural Resources Canada; Horizon 2020; Defense Advanced Research Projects Agency; H2020 Marie Skłodowska-Curie Actions; University of Toronto; Centro de Investigaciones Sociológicas; Government of Ontario; Canada Foundation for Innovation; Ontario Research Foundation","keywords":"Intersystem crossing; Excited state; Singlet state; Singlet fission; Photon upconversion; Triplet state; OLED; Fluorescence; Photochemistry; Materials science; Chemistry; Optoelectronics; Atomic physics; Luminescence; Physics; Nanotechnology; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008784684,0.0001706844,0.0002130635,0.00007044018,0.00008103828,0.0001933154,0.00009834094,0.00006778294,0.0003936556],"category_scores_gemma":[0.00003532831,0.0001496576,0.00001154786,0.0003220203,0.00007891491,0.0001308955,0.0001060734,0.0001836614,0.00006481217],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003665938,"about_ca_system_score_gemma":0.0000205546,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002590712,"about_ca_topic_score_gemma":0.000030539,"domain_scores_codex":[0.9990461,0.0000357294,0.0001546771,0.0002675914,0.000166125,0.0003297883],"domain_scores_gemma":[0.9994726,0.0001233928,0.00001745958,0.000221549,0.0000561841,0.0001088484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"observational","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002627268,0.00004987873,0.7509014,0.00135449,0.0002753249,0.0001597865,0.002262827,0.00008581104,0.2040187,0.0000114627,0.04018334,0.0006706826],"study_design_scores_gemma":[0.00178779,0.00009552779,0.1124757,0.0004177399,0.00007643562,0.00008840489,0.0003759053,0.01906357,0.8525161,0.0001096154,0.01219467,0.0007985957],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968213,0.0006642606,0.0009428751,0.0008955063,0.00003001,0.0001264452,0.00002358984,0.0001438253,0.0003521649],"genre_scores_gemma":[0.9978408,0.0001487203,0.001222456,0.0002067564,0.00005588888,0.000009116529,0.00005318792,0.00006912939,0.0003939628],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6484973,"threshold_uncertainty_score":0.610286,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007278424454488733,"score_gpt":0.1997679541155706,"score_spread":0.1924895296610819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}