{"id":"W3139307709","doi":"10.1039/d1sc00827g","title":"Donor–acceptor–acceptor-type near-infrared fluorophores that contain dithienophosphole oxide and boryl groups: effect of the boryl group on the nonradiative decay","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; Toronto Public Health","funders":"Nakatani Foundation for Advancement of Measuring Technologies in Biomedical Engineering; Japan Society for the Promotion of Science; Canada Research Chairs; Ministry of Education, Culture, Sports, Science and Technology; Kato Memorial Bioscience Foundation; Japan Agency for Medical Research and Development","keywords":"Acceptor; Group (periodic table); Infrared; Chemistry; Oxide; Photochemistry; Physics; Organic chemistry; Condensed matter physics; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001818051,0.000189245,0.0001115335,0.00009964636,0.0001017796,0.0001506718,0.0001809456,0.0002160709,0.001074459],"category_scores_gemma":[0.0001406747,0.0001088024,0.00008631919,0.0001194768,0.0001641394,0.00021281,0.0001042982,0.0002802537,0.00014519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002048092,"about_ca_system_score_gemma":0.0001307818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005177909,"about_ca_topic_score_gemma":0.0009858584,"domain_scores_codex":[0.9999563,0.000006216301,0.000002258552,0.00001418897,0.000008887277,0.00001214353],"domain_scores_gemma":[0.9999392,0.00002398183,0.00001445881,0.000004342199,0.000005364836,0.00001265886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007756781,0.00001388406,0.00005808558,0.00002944695,0.000002958978,0.00002227741,0.00001088275,0.00009210878,0.99845,0.0002471831,0.00001427515,0.0009812643],"study_design_scores_gemma":[0.00001778614,0.0001945273,0.000634588,0.000003360748,0.00000857438,0.00005702654,0.000008502867,0.001229232,0.9971421,0.00003611784,0.0006627844,0.000005276339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959947,0.0002717689,0.002284065,0.00002036402,0.00000784739,0.00001912805,0.00005792103,0.00003063881,0.001313527],"genre_scores_gemma":[0.9956304,0.0002330939,0.003448082,0.00001676614,0.0000015315,0.00001403378,0.00004044216,0.000006953095,0.0006087666],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001074459,"threshold_uncertainty_score":0.003594458,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009614824144487317,"score_gpt":0.217121420196892,"score_spread":0.2075065960524047,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}