{"id":"W3140052732","doi":"10.1039/d1dt00064k","title":"Perylene diimide-tagged <i>N</i>-heterocyclic carbene-stabilized gold nanoparticles: How much ligand desorbs from surface in presence of thiols?","year":2021,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Carbene; Diimide; Perylene; Ligand (biochemistry); Chemistry; Photochemistry; Colloidal gold; Nanoparticle; Materials science; Nanotechnology; Organic chemistry; Catalysis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001979472,0.0003270822,0.0002096847,0.0000620363,0.00008634018,0.0002378057,0.0002787465,0.0003465561,0.0004570682],"category_scores_gemma":[0.0001498381,0.0001290647,0.0001474592,0.00007885111,0.0002532853,0.0003487683,0.0001137405,0.0002636369,0.0002687566],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004796455,"about_ca_system_score_gemma":0.0001464092,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007698001,"about_ca_topic_score_gemma":0.001147605,"domain_scores_codex":[0.9998895,0.00001281854,0.000005403087,0.00004108863,0.00002863152,0.00002257773],"domain_scores_gemma":[0.9999374,0.00001566477,0.00001591624,0.000007955558,0.00001068069,0.0000123111],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004383696,0.00001183491,0.000146976,0.00007584591,0.000004209137,0.00003493025,0.0000174899,0.0000986774,0.9964065,0.0001697515,0.00004662159,0.00294332],"study_design_scores_gemma":[0.000001625243,0.0000405252,0.0003357042,0.000001879582,0.000004887169,0.00004017513,0.000007305127,0.0005301189,0.9982675,0.00003368897,0.0007339957,0.000002589187],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9751457,0.006817537,0.01391187,0.0003948936,0.00006643898,0.00003173276,0.0001235993,0.000175437,0.003332781],"genre_scores_gemma":[0.9866841,0.002954702,0.006245527,0.0001320299,0.00001672177,0.0000185403,0.0001616279,0.00002677218,0.003760066],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007698001,"threshold_uncertainty_score":0.003480017,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01580841086490015,"score_gpt":0.2335337469103002,"score_spread":0.2177253360454,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}