{"id":"W3141171895","doi":"10.1016/j.jorganchem.2021.121803","title":"Reactivity and mechanism in reactions of methylene halides with cycloneophylplatinum(II) complexes: Oxidative addition and methylene insertion","year":2021,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Methylene; Oxidative addition; Cationic polymerization; Halide; Reagent; Photochemistry; Medicinal chemistry; Insertion reaction; Reactivity (psychology); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003214776,0.0002593618,0.0006274034,0.0001270759,0.0001032249,0.00003458613,0.000106508,0.0001925055,0.0008522444],"category_scores_gemma":[0.0003480855,0.0002418715,0.00009363623,0.0004034963,0.0001161336,0.0004047795,0.0001024186,0.000541333,5.442174e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002118881,"about_ca_system_score_gemma":0.0002036144,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005725108,"about_ca_topic_score_gemma":0.00002993616,"domain_scores_codex":[0.9982748,0.00005356748,0.0007352834,0.0003288739,0.0004140241,0.0001934683],"domain_scores_gemma":[0.9978653,0.0002388492,0.001042037,0.0002671664,0.0004340762,0.0001525565],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001482684,0.000269709,0.000241662,0.0004958375,0.0001675383,0.00007857588,0.0004963187,0.000009719183,0.9951004,0.0001082821,0.000002628139,0.002881046],"study_design_scores_gemma":[0.001347542,0.00008712086,0.001906172,0.000353483,0.0001667651,0.001815565,0.003625431,0.00002326553,0.9882796,0.001746872,0.0004237351,0.0002244623],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974135,0.0006408574,0.0005698997,0.0001514438,0.00003073678,0.00005243818,0.00004931779,0.00001762179,0.001074158],"genre_scores_gemma":[0.9919497,0.0007723343,0.006831334,0.00001021798,0.00008714875,0.000006437543,0.0000514059,0.00003447439,0.0002569517],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006820827,"threshold_uncertainty_score":0.9863233,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01110837588808051,"score_gpt":0.2235689503252361,"score_spread":0.2124605744371556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}