{"id":"W3141861547","doi":"10.1039/d1sc00498k","title":"New-phase retention in colloidal core/shell nanocrystals <i>via</i> pressure-modulated phase engineering","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"nanoparticles nucleation surface interactions","field":"Earth and Planetary Sciences","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saskatoon Medical Imaging; University of Saskatchewan","funders":"China Postdoctoral Science Foundation; National Natural Science Foundation of China; People's Government of Jilin Province; Salt Science Research Foundation","keywords":"Nanocrystal; Nanomaterials; Phase (matter); Shell (structure); Colloid; Core (optical fiber); Enthalpy; Chemical engineering; Materials science; Chemical physics; Surface energy; Nanotechnology; High pressure; Chemistry; Thermodynamics; Physical chemistry; Composite material; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001996226,0.0001113113,0.0001382096,0.0000844812,0.00008910244,0.0001265886,0.000242594,0.00005432752,0.002271326],"category_scores_gemma":[0.0002641191,0.0001102635,0.00004284803,0.001417069,0.0001360046,0.0006113005,0.00002875733,0.0001467311,0.0001479153],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002464778,"about_ca_system_score_gemma":0.0001644978,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004423803,"about_ca_topic_score_gemma":0.0001003439,"domain_scores_codex":[0.9984988,0.00001544425,0.0002947329,0.0004091218,0.0003991563,0.0003827488],"domain_scores_gemma":[0.9992965,0.00009630414,0.00006166636,0.0002015062,0.00009980398,0.000244206],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003115,0.00007294662,0.002399456,0.000005107767,0.000002502806,0.00002018991,0.00005840466,0.005052318,0.9875335,0.0000220918,0.0002037908,0.004598592],"study_design_scores_gemma":[0.001036351,0.0000370461,0.003255747,0.00002328399,0.000008677242,0.00003529232,0.00003551372,0.1387982,0.852868,0.0001988676,0.003552729,0.00015028],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975004,0.0001696503,0.0007711404,0.0001881321,0.0003285389,0.0001135699,0.00002805059,0.00006710637,0.0008334211],"genre_scores_gemma":[0.9963587,0.000005718538,0.003074925,0.00006311931,0.00005055473,9.541636e-7,0.00003979302,0.000003491714,0.00040275],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1346654,"threshold_uncertainty_score":0.9986407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01871363689195948,"score_gpt":0.2692030130704912,"score_spread":0.2504893761785317,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}