{"id":"W3151633697","doi":"10.1016/j.bej.2021.108010","title":"Study on the electron transfer capability of porphyrin ring and the mechanisms in the catalytic denitrification","year":2021,"lang":"en","type":"article","venue":"Biochemical Engineering Journal","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"Concordia University","funders":"","keywords":"Porphyrin; Electron transfer; Chemistry; Denitrification; Tetraphenylporphyrin; Photochemistry; Electron transport chain; Catalysis; Redox; Oxidizing agent; Inorganic chemistry; Organic chemistry; Nitrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001605671,0.0001799177,0.0001713152,0.0001053182,0.0001567235,0.000179854,0.0002817787,0.0002457087,0.0007519345],"category_scores_gemma":[0.00020262,0.00008937499,0.0001612981,0.0001518211,0.0002203234,0.0003940909,0.0001270422,0.0004289618,0.0001039329],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002883015,"about_ca_system_score_gemma":0.00017807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009673513,"about_ca_topic_score_gemma":0.0003614446,"domain_scores_codex":[0.9999522,0.000007062548,0.000001691991,0.0000114675,0.00001103475,0.00001655116],"domain_scores_gemma":[0.9999498,0.0000229203,0.000006210803,0.000006219825,0.000007836088,0.000007026174],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000157025,0.00005800651,0.0005889967,0.0001673029,0.00001112258,0.0002298474,0.00006293923,0.0007757397,0.9881772,0.002497437,0.00008087618,0.007193503],"study_design_scores_gemma":[0.000009719176,0.0001467891,0.002838226,0.000008123294,0.00001479515,0.0002346447,0.00006791232,0.006152274,0.9876702,0.0005815897,0.002267953,0.000007673894],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894556,0.003217515,0.004256399,0.0001879867,0.00001432796,0.00001241295,0.00005276421,0.00002098509,0.002782049],"genre_scores_gemma":[0.9961648,0.001185172,0.001048463,0.00001463578,0.000003738153,0.00000458278,0.00004811573,0.000003068037,0.00152756],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009673513,"threshold_uncertainty_score":0.002515495,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01299471592117705,"score_gpt":0.2232707571035085,"score_spread":0.2102760411823314,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}