{"id":"W3154612615","doi":"10.1039/d1qo00359c","title":"Photo-induced transition-metal and external photosensitizer-free organic reactions","year":2021,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Higher Education Discipline Innovation Project; National Natural Science Foundation of China; International Joint Research Center for Green Catalysis and Synthesis","keywords":"Chemistry; Photosensitizer; Scope (computer science); Transition metal; Photochemistry; Nanotechnology; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009234557,0.0004195536,0.0004704689,0.00002741411,0.0004653421,0.0002104778,0.0003623107,0.0004503406,0.02145895],"category_scores_gemma":[0.0007771939,0.0004932079,0.0002291815,0.0004144781,0.0002101679,0.0001976448,0.0001441357,0.0008916304,0.00004485126],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003964519,"about_ca_system_score_gemma":0.0003018215,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006327978,"about_ca_topic_score_gemma":0.00000986412,"domain_scores_codex":[0.9975555,0.0000213677,0.0005173539,0.0008723503,0.0004670298,0.0005663884],"domain_scores_gemma":[0.9979187,0.0001166274,0.0001557854,0.001071758,0.0001562262,0.0005809033],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003633073,0.0001777928,0.00002942341,0.0001527783,0.0001591978,0.000174611,0.00009423708,4.325906e-7,0.9941356,0.000003596642,0.004421448,0.00061455],"study_design_scores_gemma":[0.001336623,0.000007101226,0.00003303251,0.00009396675,0.0001859324,0.001085419,0.001016386,0.0001488207,0.9825795,0.0008220979,0.01218565,0.0005054818],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9712266,0.0004794908,0.001118046,0.0007725056,0.0002514282,0.00009081,0.0001004834,0.0003066423,0.02565397],"genre_scores_gemma":[0.9827498,0.0001842046,0.002228927,0.0002538656,0.0004942346,0.00003696545,0.0001783418,0.0001292049,0.01374447],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0214141,"threshold_uncertainty_score":0.999752,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006346070230267876,"score_gpt":0.2027920831692064,"score_spread":0.1964460129389386,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}