{"id":"W3157581895","doi":"10.1039/d1sc01146d","title":"Total synthesis, isolation, surfactant properties, and biological evaluation of ananatosides and related macrodilactone-containing rhamnolipids","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Chicoutimi; Institut National de la Recherche Scientifique","funders":"Fonds de recherche du Québec – Nature et technologies; Fonds de Recherche du Québec - Santé; Microbiology Society; Liverpool John Moores University; Centre National de la Recherche Scientifique; Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation; Natural Sciences and Engineering Research Council of Canada; Université de Sherbrooke","keywords":"Pulmonary surfactant; Isolation (microbiology); Chemistry; Microbiology; Biology; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007555793,0.0001344351,0.0002251466,0.00002256082,0.0001273406,0.0000597255,0.0001269252,0.0001428583,0.0004386879],"category_scores_gemma":[0.00318561,0.0001088525,0.00003724891,0.0003093105,0.0008801394,0.0002000311,0.0001593755,0.0001293279,8.420977e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009378821,"about_ca_system_score_gemma":0.0002284589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001653567,"about_ca_topic_score_gemma":7.819248e-7,"domain_scores_codex":[0.9985287,0.00002846451,0.0003004844,0.0004863098,0.0004141857,0.0002419103],"domain_scores_gemma":[0.9990563,0.0001993515,0.0001007676,0.0002172823,0.0002894765,0.0001367677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002078453,0.00002948953,0.004652242,0.00004474067,0.00001106922,0.00000261773,0.0001854776,0.000004574259,0.9911605,0.00006382896,0.000001908702,0.003822793],"study_design_scores_gemma":[0.0001796331,0.000005025744,0.00173785,0.0001046086,0.00003953266,0.00007782536,0.0003992162,0.006683297,0.9902893,0.0003231135,0.000008972711,0.000151613],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945362,0.001040521,0.000002443872,0.0001316192,0.00002351276,0.00003742978,0.000008970675,0.00002781534,0.004191501],"genre_scores_gemma":[0.9996954,0.00007420724,0.0001466859,0.000008185322,0.00002077911,0.00001057937,0.000005755898,0.000005777962,0.00003261389],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006678722,"threshold_uncertainty_score":0.4803325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04707538637424889,"score_gpt":0.2512705003599378,"score_spread":0.2041951139856888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}