{"id":"W3157581895","doi":"10.1039/d1sc01146d","title":"Total synthesis, isolation, surfactant properties, and biological evaluation of ananatosides and related macrodilactone-containing rhamnolipids","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Chicoutimi; Institut National de la Recherche Scientifique","funders":"Fonds de recherche du Québec – Nature et technologies; Fonds de Recherche du Québec - Santé; Microbiology Society; Liverpool John Moores University; Centre National de la Recherche Scientifique; Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation; Natural Sciences and Engineering Research Council of Canada; Université de Sherbrooke","keywords":"Pulmonary surfactant; Isolation (microbiology); Chemistry; Microbiology; Biology; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00025549,0.000392831,0.0001488324,0.0002141316,0.0001670931,0.0002821231,0.0001693536,0.0001440151,0.0006757572],"category_scores_gemma":[0.0002561263,0.00007767805,0.000171874,0.0002394621,0.0001729316,0.000265713,0.0002033005,0.0003285984,0.0002886031],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002339189,"about_ca_system_score_gemma":0.0003153109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000626788,"about_ca_topic_score_gemma":0.0009847953,"domain_scores_codex":[0.9998956,0.00002603527,0.00001138751,0.00002107588,0.00003191018,0.00001397517],"domain_scores_gemma":[0.9998307,0.00004072669,0.00003292249,0.00002372868,0.00004352874,0.00002836324],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003345868,0.000004138766,0.00004009245,0.00001846987,0.000002604603,0.00001056241,0.000009423937,0.00003937301,0.9987785,0.00003926113,0.000005194425,0.001018837],"study_design_scores_gemma":[0.00000154141,0.00005791566,0.0002375629,0.000001945357,0.000006442024,0.00002970382,0.000005803211,0.00008281285,0.9989548,0.00001741094,0.000602227,0.000001878218],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9709938,0.004041493,0.02111068,0.00008079183,0.00003140604,0.0001110834,0.0009271354,0.0001039368,0.002599633],"genre_scores_gemma":[0.9785162,0.002947437,0.01399686,0.00005932284,0.00001242305,0.00007934125,0.001354779,0.00005437294,0.002979227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006757572,"threshold_uncertainty_score":0.002260685,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04707538637424889,"score_gpt":0.2512705003599378,"score_spread":0.2041951139856888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}