{"id":"W3157628690","doi":"10.1002/chem.202101132","title":"Electrochemical Hydroboration of Alkynes","year":2021,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Région Normandie; Université de Rouen; Centre National de la Recherche Scientifique; Normandie Université; Agence Nationale de la Recherche; Institut Universitaire de France; Indian National Science Academy","keywords":"Hydroboration; Alkyne; Electrochemistry; Chemistry; Boron; Hydride; Catalysis; Metal; Organic chemistry; Electrode; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000193081,0.0001811028,0.0002275132,0.000014228,0.0001025917,0.00006481152,0.0003185913,0.00007817602,0.004687887],"category_scores_gemma":[0.0009372714,0.0001835009,0.0002132803,0.00018803,0.0001306597,0.00009684132,0.0000774022,0.0008383591,0.00004157465],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001045368,"about_ca_system_score_gemma":0.0001859799,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":3.879378e-7,"about_ca_topic_score_gemma":6.938981e-8,"domain_scores_codex":[0.9984859,0.00004432308,0.0005474564,0.0002699282,0.0003493479,0.0003030159],"domain_scores_gemma":[0.9987035,0.00008811255,0.0002702002,0.0003586803,0.0002600864,0.0003194121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002326204,0.0001441958,0.00006046084,0.00008320305,0.00005399393,0.0002046527,0.00003606699,0.000004694956,0.9965324,0.000008764625,0.001689276,0.001158964],"study_design_scores_gemma":[0.0004888977,0.000006773323,0.00002396192,0.0001041669,0.00004043315,0.001640371,0.00008293256,0.0002654507,0.9783233,0.0002224171,0.01862638,0.0001748971],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8553991,0.0004271239,0.001078033,0.0002935874,0.00004897479,0.00001495331,0.000008654672,0.00006279837,0.1426667],"genre_scores_gemma":[0.9950572,0.000103093,0.001318022,0.00005876075,0.000693893,0.000001888371,0.00006455112,0.00004669632,0.002655926],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1400108,"threshold_uncertainty_score":0.996222,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00969962140175347,"score_gpt":0.2220970695382747,"score_spread":0.2123974481365212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}