{"id":"W3157628690","doi":"10.1002/chem.202101132","title":"Electrochemical Hydroboration of Alkynes","year":2021,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Région Normandie; Université de Rouen; Centre National de la Recherche Scientifique; Normandie Université; Agence Nationale de la Recherche; Institut Universitaire de France; Indian National Science Academy","keywords":"Hydroboration; Alkyne; Electrochemistry; Chemistry; Boron; Hydride; Catalysis; Metal; Organic chemistry; Electrode; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001178602,0.0002603544,0.0002253027,0.0001541692,0.0001410512,0.0002238289,0.0002518566,0.0002323118,0.002042923],"category_scores_gemma":[0.0001741978,0.0001369628,0.0001577979,0.000102702,0.0001937934,0.0002918638,0.0003743812,0.000430887,0.0004843193],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001279009,"about_ca_system_score_gemma":0.0001111311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002923885,"about_ca_topic_score_gemma":0.0007221038,"domain_scores_codex":[0.9998634,0.00001707321,0.000009248471,0.0000313664,0.00003629943,0.00004252593],"domain_scores_gemma":[0.9999551,0.000009822608,0.000008892726,0.000007758009,0.00000910863,0.000009322956],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006632166,0.0000116978,0.00009107383,0.0001975717,0.00001787714,0.00009487419,0.00005149432,0.0001210266,0.991879,0.0004707496,0.0001632148,0.006835129],"study_design_scores_gemma":[0.0000122418,0.00008213708,0.0003000707,0.000008002701,0.000009302766,0.0001105388,0.00002192016,0.0002627847,0.9943092,0.00009586464,0.004781391,0.000006633257],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9542781,0.007567664,0.02519989,0.0004198967,0.0003265401,0.00008984355,0.0002666237,0.00025166,0.0115999],"genre_scores_gemma":[0.9918899,0.001642362,0.002978145,0.00009065127,0.0000165868,0.00001315301,0.00006556728,0.0000238422,0.003279948],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002042923,"threshold_uncertainty_score":0.006834269,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00969962140175347,"score_gpt":0.2220970695382747,"score_spread":0.2123974481365212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}