{"id":"W3157721934","doi":"10.1002/celc.202100369","title":"Ultrasensitive Detection of Surface‐Confined Redox Molecules by Mediation‐Based Amplification","year":2021,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Ferrocene; Monolayer; Redox; Ferrocyanide; Voltammetry; Chemistry; Cyclic voltammetry; Detection limit; Supporting electrolyte; Electrochemistry; Electrocatalyst; Molecule; Analytical Chemistry (journal); Inorganic chemistry; Electrode; Physical chemistry; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007248732,0.0001872684,0.0002743987,0.0000291926,0.00009070519,0.00002228876,0.0001406743,0.0001638567,0.0002817911],"category_scores_gemma":[0.0001707534,0.0002041153,0.0001651893,0.0005896647,0.00006593926,0.0000434382,0.00001592998,0.0002043549,0.00001778632],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001018715,"about_ca_system_score_gemma":0.000118761,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001236625,"about_ca_topic_score_gemma":0.0000124343,"domain_scores_codex":[0.9986075,0.00001825738,0.0003887684,0.000437738,0.0002731084,0.000274697],"domain_scores_gemma":[0.9987264,0.000150101,0.0002456767,0.0004046043,0.0003789522,0.00009429745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002682149,0.0001757496,0.00004018683,0.00004978705,0.0000716092,6.25193e-7,0.00002940706,0.00001746257,0.9982312,0.0001555447,0.0003314882,0.0008701114],"study_design_scores_gemma":[0.0003536131,0.00001275636,0.00002235242,0.0000135773,0.00007901486,0.000003354754,0.00007334897,0.003129064,0.9943399,0.0003641075,0.001410548,0.0001984029],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9565852,0.0006442589,0.03788705,0.0006314964,0.000009057158,0.00006618949,0.00005052689,0.0001169071,0.00400928],"genre_scores_gemma":[0.9964923,0.00007489585,0.00117559,0.0001042491,0.00006034861,0.00003554403,0.001504326,0.00002479693,0.0005279514],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03990706,"threshold_uncertainty_score":0.8323579,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005072581049634623,"score_gpt":0.2149397069727051,"score_spread":0.2098671259230705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}