{"id":"W3158544329","doi":"10.1021/acscatal.1c00288","title":"<sup>DMP</sup> DAB–Pd–MAH: A Versatile Pd(0) Source for Precatalyst Formation, Reaction Screening, and Preparative-Scale Synthesis","year":2021,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphine; Ligand (biochemistry); Catalysis; Palladium; Denticity; Chemistry; Microscale chemistry; Coupling reaction; Chelation; Maleic anhydride; Combinatorial chemistry; Organic chemistry; Metal; Copolymer; Polymer; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003176003,0.000383414,0.00055068,0.0001703411,0.0006486557,0.0003134147,0.0002772672,0.0002777089,0.0002348158],"category_scores_gemma":[0.001177528,0.0004271975,0.0003499027,0.0005688221,0.0001829179,0.0009453215,0.000213133,0.0002644877,0.00007563884],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002841596,"about_ca_system_score_gemma":0.0001308706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004458912,"about_ca_topic_score_gemma":0.0003890791,"domain_scores_codex":[0.9975649,0.000006807647,0.000660021,0.0008579707,0.0004268801,0.000483408],"domain_scores_gemma":[0.9969274,0.0008613293,0.0003895086,0.001188767,0.0004268562,0.000206109],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003510426,0.0006136023,0.002981027,0.0008800143,0.001623183,0.00001548216,0.01343496,0.002808069,0.9327248,0.00004918627,0.009725471,0.03479315],"study_design_scores_gemma":[0.0008331163,0.00001736053,0.0003477133,0.0001351139,0.001296483,0.0001620052,0.006589111,0.02433443,0.9327515,0.00006191942,0.03294208,0.0005291314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907981,0.0003088462,0.005910754,0.0004145594,0.00005003762,0.0002626213,0.0005163584,0.0002858413,0.001452875],"genre_scores_gemma":[0.9876151,0.00007252409,0.0008779943,0.00004071075,0.000241231,0.0004576643,0.00330529,0.00007920188,0.00731025],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03426401,"threshold_uncertainty_score":0.999818,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01577182543901265,"score_gpt":0.2587352017703817,"score_spread":0.242963376331369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}