{"id":"W3158544329","doi":"10.1021/acscatal.1c00288","title":"<sup>DMP</sup> DAB–Pd–MAH: A Versatile Pd(0) Source for Precatalyst Formation, Reaction Screening, and Preparative-Scale Synthesis","year":2021,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphine; Ligand (biochemistry); Catalysis; Palladium; Denticity; Chemistry; Microscale chemistry; Coupling reaction; Chelation; Maleic anhydride; Combinatorial chemistry; Organic chemistry; Metal; Copolymer; Polymer; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001880571,0.0004648558,0.0002060424,0.0002021458,0.0001564942,0.0002322444,0.0005178496,0.0002304065,0.002225897],"category_scores_gemma":[0.0002377307,0.0002111154,0.0001173846,0.0002020807,0.0001806017,0.0002706166,0.0002662412,0.0004410912,0.001890335],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001746201,"about_ca_system_score_gemma":0.0001501974,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002119549,"about_ca_topic_score_gemma":0.0005738865,"domain_scores_codex":[0.999849,0.0000196978,0.00001464071,0.00003807432,0.00005818544,0.00002044824],"domain_scores_gemma":[0.9998784,0.00002844185,0.00002804119,0.00002385101,0.00002179302,0.00001950249],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001115625,0.00001715582,0.0001422878,0.0001201134,0.000008772008,0.0001230565,0.00002622147,0.000140943,0.988887,0.0003688839,0.0004085325,0.009645584],"study_design_scores_gemma":[0.000004855321,0.00005239853,0.0001818252,0.000001777937,0.00000333736,0.0001907301,0.000004725605,0.0002319108,0.99534,0.00003323251,0.003952436,0.000002728091],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7888678,0.005930767,0.1756335,0.0004890249,0.0001334024,0.0004074013,0.003016862,0.004429658,0.02109155],"genre_scores_gemma":[0.9094144,0.001941375,0.07791489,0.0001375532,0.00004449618,0.0001872403,0.002429974,0.0004291565,0.007501086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002225897,"threshold_uncertainty_score":0.007446408,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01577182543901265,"score_gpt":0.2587352017703817,"score_spread":0.242963376331369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}