{"id":"W3159524212","doi":"10.1007/s00396-021-04838-1","title":"Novel perfluoropolyalkylethers monomers: synthesis and photo-induced cationic polymerization","year":2021,"lang":"en","type":"article","venue":"Colloid & Polymer Science","topic":"Synthesis and properties of polymers","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; Trinity Western University; Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Horizon 2020 Framework Programme; European Commission; Politecnico di Torino","keywords":"Cationic polymerization; Photopolymer; Polymerization; Monomer; Polymer chemistry; Thermal stability; Materials science; Yield (engineering); Chemistry; Chemical engineering; Organic chemistry; Polymer; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006691339,0.0002729299,0.0003107151,0.000205178,0.000977654,0.0005730249,0.0006573927,0.00009073359,0.001460585],"category_scores_gemma":[0.0004452738,0.0002536837,0.00007601582,0.001086743,0.001036644,0.0009175052,0.0002645078,0.00009963927,0.0001162278],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001310521,"about_ca_system_score_gemma":0.001015793,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008604311,"about_ca_topic_score_gemma":0.00003939159,"domain_scores_codex":[0.9972393,0.00008835647,0.0003772673,0.0009421064,0.0006685492,0.0006844384],"domain_scores_gemma":[0.9984505,0.0001855629,0.0001728692,0.000683102,0.0001801818,0.0003277823],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001626932,0.00006032399,0.0002534895,0.00001079553,0.000007282137,0.000002301081,0.000590995,0.000001607632,0.9799968,0.0005151335,0.0000275664,0.01851745],"study_design_scores_gemma":[0.0001921845,0.00003896038,0.001097277,0.00004361708,0.00003278691,0.00004755908,0.001282083,0.0004249659,0.9961767,0.00001087918,0.0002970025,0.0003559898],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9854376,0.006912927,0.000302678,0.001033595,0.0008537355,0.0001652256,0.00002278708,0.0001072829,0.005164138],"genre_scores_gemma":[0.9969196,0.0001138937,0.0009126565,0.0006674579,0.00009527212,0.00007212623,0.000001939696,0.0000317914,0.001185244],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01816146,"threshold_uncertainty_score":0.9999915,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02029874673593659,"score_gpt":0.2400349044899076,"score_spread":0.219736157753971,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}