{"id":"W3161202743","doi":"10.1002/anie.202105909","title":"Facile Synthesis of Cyanide and Isocyanides from CO","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Isocyanide; Chemistry; Steric effects; Substituent; Cyanide; Aryl; Silylation; Alkyl; Salt (chemistry); Medicinal chemistry; Alkali metal; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001224739,0.0003498079,0.0002659634,0.0002807798,0.0002565256,0.0002265531,0.0003770936,0.0001834915,0.002698543],"category_scores_gemma":[0.0001406017,0.0001371296,0.0001206377,0.0003585742,0.0001272548,0.0002064191,0.0003255047,0.0003961616,0.001412519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005687345,"about_ca_system_score_gemma":0.0005378923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001145816,"about_ca_topic_score_gemma":0.003824122,"domain_scores_codex":[0.9998875,0.00000960731,0.000007201736,0.00002162292,0.00003735907,0.00003677994],"domain_scores_gemma":[0.9999282,0.000006009446,0.000008734341,0.00001128548,0.0000257099,0.00002000377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002111217,0.00007912552,0.0003790843,0.0002878707,0.00001345602,0.0004435996,0.000125358,0.0007279887,0.9677019,0.004913853,0.0014624,0.02365418],"study_design_scores_gemma":[0.00001602098,0.0001210468,0.0007848961,0.00001035847,0.000005422168,0.0001730674,0.00001818219,0.000613191,0.9832977,0.0001737376,0.01477554,0.00001076518],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8652271,0.003039836,0.03396378,0.0002788122,0.0002754993,0.0003598735,0.001862133,0.000580648,0.09441226],"genre_scores_gemma":[0.9744032,0.00178841,0.0110218,0.00006741901,0.00001618317,0.0001130213,0.0009352815,0.000120378,0.01153432],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002698543,"threshold_uncertainty_score":0.009027541,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01112934077709357,"score_gpt":0.2417244730781986,"score_spread":0.230595132301105,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}