{"id":"W3162300958","doi":"10.1039/d1sc01906f","title":"Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Basic Energy Sciences; Azrieli Foundation; Chemical Sciences, Geosciences, and Biosciences Division; Canadian Institute for Advanced Research; Division of Chemistry; Camille and Henry Dreyfus Foundation; Alfred P. Sloan Foundation; U.S. Department of Energy; National Science Foundation","keywords":"Thorium; Uranium; Cyclopentadienyl complex; Tris; Electrochemistry; Chemistry; Inorganic chemistry; Radiochemistry; Organic chemistry; Electrode; Materials science; Metallurgy; Physical chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003260151,0.00009911876,0.0001622568,0.00001528037,0.0001100868,0.00006516113,0.000195712,0.00003745408,0.00002867763],"category_scores_gemma":[0.0004012957,0.00007325547,0.00001620238,0.0003431391,0.0008718738,0.0001798721,0.0001075064,0.0001558793,1.766065e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000451507,"about_ca_system_score_gemma":0.00005333604,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003581817,"about_ca_topic_score_gemma":0.000001426726,"domain_scores_codex":[0.9990085,0.00001231119,0.0001928409,0.0003189501,0.0002432078,0.0002242196],"domain_scores_gemma":[0.9993672,0.0002874355,0.00006840268,0.0001252843,0.0001003866,0.00005126994],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001726399,0.00003098494,0.002565047,0.0001428501,0.000006286652,0.000002433515,0.000874669,1.438713e-7,0.9954587,0.0001233964,0.0000265115,0.0007516655],"study_design_scores_gemma":[0.0002506289,0.000005564389,0.0003411916,0.00005313948,0.00001088869,0.00003522671,0.003118426,0.0000728125,0.99433,0.001449555,0.000242778,0.00008973867],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958376,0.001916465,0.00002323291,0.0004237706,0.00000950712,0.00002571006,0.000002536258,0.000007807702,0.001753345],"genre_scores_gemma":[0.9991264,0.0003130188,0.0004167673,0.00005872948,0.00003539215,0.000006866726,0.0000103558,0.000003069259,0.00002942221],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003288753,"threshold_uncertainty_score":0.3212455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02474879270097766,"score_gpt":0.3094331888729921,"score_spread":0.2846843961720144,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}