{"id":"W3163249056","doi":"10.5194/amt-14-5859-2021","title":"Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride","year":2021,"lang":"en","type":"article","venue":"Atmospheric measurement techniques","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland; York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Analytical Chemistry (journal); Detection limit; Mixing ratio; Cavity ring-down spectroscopy; Troposphere; Spectrometer; Hydrogen chloride; Relative humidity; Analyser; Atmosphere (unit); Chloride; Laser; Environmental chemistry; Meteorology; Optics; Chromatography; Physics; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003554809,0.0008596321,0.0005647563,0.0005263574,0.0005337748,0.0004931998,0.001571174,0.001204889,0.0007158277],"category_scores_gemma":[0.002382544,0.0003859874,0.000638809,0.0002731846,0.0005735677,0.0006473785,0.0008667813,0.0006665238,0.0004794057],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006866594,"about_ca_system_score_gemma":0.001179465,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004504294,"about_ca_topic_score_gemma":0.005993912,"domain_scores_codex":[0.9972144,0.0003948582,0.0001297659,0.0008453152,0.001300453,0.0001152608],"domain_scores_gemma":[0.9987633,0.0003104186,0.0001018492,0.0001758426,0.0005740096,0.00007458906],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001425476,0.00007917619,0.002144519,0.00008497306,0.0000264602,0.00003671197,0.00006302768,0.0003980149,0.9900142,0.0000898104,0.0001563103,0.006764363],"study_design_scores_gemma":[0.00009816056,0.001273381,0.008051994,0.00002609119,0.0000612222,0.0003283776,0.00005533365,0.0126,0.9727063,0.00005761669,0.004689982,0.00005147266],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8197845,0.001106173,0.17148,0.0003050774,0.00032967,0.001222822,0.002079207,0.001629168,0.002063442],"genre_scores_gemma":[0.6847644,0.000785987,0.3082409,0.0004636656,0.00006420182,0.0007339456,0.00210395,0.0001849004,0.002658125],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.004504294,"threshold_uncertainty_score":0.01879984,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03631714727701468,"score_gpt":0.2273622308631243,"score_spread":0.1910450835861096,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}