{"id":"W3163671043","doi":"","title":"[Co III (acacen)(thioacetamide) 2 ]ClO 4 及び[Co III ((BA) 2 )en)(thioacetamide) 2 ]PF 6 の合成,キャラクタリゼーション,及び単結晶X線構造 [Co III (acacen)(thioacetamide) 2 ]ClO 4 のソルバトクロミック特性","year":2005,"lang":"ja","type":"article","venue":"Canadian Journal of Chemistry","topic":"Crystal structures of chemical compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Thioacetamide; Chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.003289359,0.005221583,0.006560124,0.001227625,0.002400445,0.002594118,0.009454604,0.006288733,0.03172151],"category_scores_gemma":[0.002332532,0.005948359,0.004530069,0.002089065,0.003783394,0.002682691,0.0006475769,0.01455606,0.0006573006],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.009829901,"about_ca_system_score_gemma":0.01302887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003099999,"about_ca_topic_score_gemma":0.004749248,"domain_scores_codex":[0.9739924,0.0005779139,0.008636243,0.003982986,0.005142763,0.007667703],"domain_scores_gemma":[0.9719227,0.001636668,0.006357829,0.005216051,0.002329746,0.01253702],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001640876,0.0006417557,0.002359282,0.002698575,0.003267404,0.0042088,0.004693338,0.001316706,0.7165478,0.0001304512,0.2570605,0.005434553],"study_design_scores_gemma":[0.01083038,0.0001804465,0.0002661812,0.001999478,0.001123925,0.005352991,0.003348463,0.0002629047,0.4855559,0.0004141281,0.4864183,0.004246814],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7945163,0.01968215,0.0001133745,0.01031105,0.002205052,0.001040649,0.001433127,0.0004190266,0.1702793],"genre_scores_gemma":[0.9425399,0.001857855,0.0009757162,0.003220693,0.0143672,0.00006237238,0.00102956,0.001081381,0.03486527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2309918,"threshold_uncertainty_score":0.9989277,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008343766591876012,"score_gpt":0.2398175932752278,"score_spread":0.2314738266833518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}