{"id":"W3163761805","doi":"10.1039/d1cc02245h","title":"Constructing fused N-heterocycles from unprotected mesoionic N-heterocyclic olefins and organic azides <i>via</i> diazo transfer","year":2021,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; Consejo Nacional de Ciencia y Tecnología","keywords":"Mesoionic; Diazo; Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007010329,0.0002354679,0.0001232337,0.00009559113,0.00009979062,0.0001845059,0.0002587161,0.0002261879,0.001202215],"category_scores_gemma":[0.0001015087,0.00007913812,0.0001435899,0.00008982021,0.0001609416,0.0002979292,0.0002269531,0.0002956314,0.0003725832],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002260724,"about_ca_system_score_gemma":0.0001243049,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000254533,"about_ca_topic_score_gemma":0.0007021845,"domain_scores_codex":[0.9999585,0.000004132362,0.000002554287,0.00001367543,0.000008940785,0.00001221872],"domain_scores_gemma":[0.9999735,0.000006008182,0.000009617809,0.000003642597,0.000002589025,0.000004569991],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001379552,0.00007778146,0.0003616275,0.0004775004,0.00002665919,0.0004784734,0.00008701595,0.002137619,0.9686876,0.009263002,0.0004643748,0.01780033],"study_design_scores_gemma":[0.00003820883,0.0007558105,0.001140644,0.00002279498,0.0000253318,0.0004400379,0.00003580772,0.003940974,0.9708824,0.0009277436,0.0217694,0.00002082798],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9618189,0.00383195,0.0156433,0.0001020864,0.0001046975,0.00009881938,0.0003323429,0.0001752154,0.01789282],"genre_scores_gemma":[0.9888177,0.001949047,0.00610988,0.00004422915,0.00000996809,0.00004224788,0.0002033885,0.00002354519,0.002800023],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001202215,"threshold_uncertainty_score":0.004021823,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0200491578595593,"score_gpt":0.231335206288283,"score_spread":0.2112860484287237,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}