{"id":"W316379055","doi":"10.1023/a:1022925216642","title":"Soret Coefficients for Aqueous Polyethylene Glycol Solutions and Some Tests of the Segmental Model of Polymer Thermal Diffusion","year":2003,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Field-Flow Fractionation Techniques","field":"Engineering","cited_by":72,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Triethylene glycol; Chemistry; Ethylene glycol; Alkane; Diethylene glycol; Solvent; Analytical Chemistry (journal); Diffusion; Toluene; Aqueous solution; Thermodynamics; Polyethylene glycol; Thermal diffusivity; Polystyrene; Activation energy; Polymer chemistry; Chromatography; Polymer; Physical chemistry; Hydrocarbon; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001703248,0.00008971542,0.0001429629,0.00003987167,0.00007055901,0.000005918999,0.0000992848,0.0001144932,0.00001596262],"category_scores_gemma":[0.00007669676,0.0000745561,0.0001029886,0.0000698191,0.00007204407,0.0001211826,0.00002153327,0.0001573005,1.013886e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008825849,"about_ca_system_score_gemma":0.00005861818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002496747,"about_ca_topic_score_gemma":3.112463e-7,"domain_scores_codex":[0.9992312,0.00001212939,0.0003609486,0.00006061472,0.0002116031,0.0001234824],"domain_scores_gemma":[0.9994416,0.00005277124,0.0002347786,0.0001033471,0.0001259943,0.00004146692],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001743429,0.00008231254,0.0002855748,0.00008160538,0.00002495578,1.423657e-7,0.00005947408,0.007610121,0.990912,0.00009678457,0.0003709429,0.0004586312],"study_design_scores_gemma":[0.0004948875,0.00002562341,0.0002623794,0.00006578061,0.00002807883,0.00003472518,0.00005631662,0.04210004,0.9564986,0.0003281567,0.00003687283,0.00006860218],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9640501,0.0009829949,0.03421777,0.0001051394,0.0001437233,0.0001202253,0.00004481187,0.00002250019,0.0003127182],"genre_scores_gemma":[0.9984214,0.00006378445,0.001346546,0.00001604925,0.00004350819,0.000005364378,0.000001859328,0.00001320079,0.0000882458],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03448991,"threshold_uncertainty_score":0.304031,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01155588395523284,"score_gpt":0.2232770027222201,"score_spread":0.2117211187669872,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}