{"id":"W3163797354","doi":"10.1002/zaac.202100073","title":"Tridentate NPN Ligands with a Central Secondary Phosphine Oxide Donor and their Corresponding Metal Complexes","year":2021,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University; University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Denticity; Chemistry; Ruthenium; Ligand (biochemistry); Intramolecular force; Nickel; Deprotonation; Metal; Phosphine; Stereochemistry; Hydrogen bond; Crystal structure; Crystallography; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009877214,0.0001996378,0.0001863157,0.0001355919,0.0001218733,0.0003006419,0.0005122774,0.0002099193,0.001845548],"category_scores_gemma":[0.0002262535,0.000140114,0.00008994697,0.0001221832,0.0001742424,0.0002252112,0.0002584104,0.0002485299,0.0004789252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004751225,"about_ca_system_score_gemma":0.000161833,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004743867,"about_ca_topic_score_gemma":0.0007471698,"domain_scores_codex":[0.9998516,0.00002834069,0.000009660731,0.00003742534,0.00004483953,0.00002820651],"domain_scores_gemma":[0.9999316,0.00001070137,0.00001672641,0.00001091464,0.0000123474,0.00001771287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002985584,0.00006412705,0.0001840639,0.0002794279,0.00001464366,0.0001579738,0.00006154518,0.0003931187,0.9903091,0.001150939,0.0003068663,0.0067797],"study_design_scores_gemma":[0.00002889081,0.0002728107,0.0006202035,0.00000992725,0.00001372703,0.0003203289,0.00002334908,0.001174925,0.9903598,0.00009001912,0.007077073,0.000008894131],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9777896,0.00240658,0.005986523,0.0001136043,0.00004527951,0.0000661408,0.0002973821,0.0001994215,0.01309547],"genre_scores_gemma":[0.986968,0.0004518743,0.004656494,0.00004252432,0.00000548673,0.00004922024,0.0004428901,0.00003571517,0.007347698],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001845548,"threshold_uncertainty_score":0.006173968,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008779857617987394,"score_gpt":0.2258455435841612,"score_spread":0.2170656859661738,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}