{"id":"W3166501182","doi":"10.1002/chem.202101534","title":"Bipyridinium and Phenanthrolinium Dications for Metal‐Free Hydrodefluorination: Distinctive Carbon‐Based Reactivity","year":2021,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Hydride; Lewis acids and bases; Reactivity (psychology); Medicinal chemistry; Carbocation; Delocalized electron; Aryl; Stereochemistry; Alkyl; Catalysis; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001245323,0.0002912576,0.0001725541,0.0001100227,0.0001091194,0.0001360555,0.0002152413,0.0002435731,0.001178469],"category_scores_gemma":[0.0001006213,0.0001166558,0.0001072209,0.00008919432,0.0001486476,0.000171546,0.0002848966,0.0003400215,0.0003584828],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001606902,"about_ca_system_score_gemma":0.00007018489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001407783,"about_ca_topic_score_gemma":0.0003722824,"domain_scores_codex":[0.9999018,0.00001442373,0.000006623392,0.00002115967,0.00002748741,0.00002840342],"domain_scores_gemma":[0.9999437,0.000007672285,0.00001354056,0.000009187087,0.00001012128,0.0000156549],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007990902,0.000007789347,0.00003866389,0.0000728329,0.000004248332,0.00004786658,0.00001726617,0.0001049966,0.9969482,0.0002433303,0.0001014211,0.002333482],"study_design_scores_gemma":[0.00001688623,0.0002410324,0.0004216864,0.000003475374,0.000004679581,0.000148655,0.000006055989,0.0003377283,0.995407,0.00004493004,0.003361678,0.000006328949],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876039,0.001463951,0.005054655,0.0001144654,0.0000470939,0.00004657343,0.0002798836,0.0001140686,0.005275472],"genre_scores_gemma":[0.9932294,0.0005450872,0.004256117,0.00004828183,0.00001009085,0.00002245007,0.000182089,0.00002173113,0.001684797],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001178469,"threshold_uncertainty_score":0.00394237,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08665313850712439,"score_gpt":0.3828103475274186,"score_spread":0.2961572090202942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}