{"id":"W3168863578","doi":"10.1021/acs.chemmater.1c00917","title":"Building a <b>shp</b> : A Rare-Earth Metal–Organic Framework and Its Application in a Catalytic Photooxidation Reaction","year":2021,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":71,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Concordia University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Linker; Sulfoxide; Catalysis; Metal-organic framework; Sulfide; Pyrene; Benzoic acid; Chemistry; Rare earth; Photocatalysis; Sulfur; Topology (electrical circuits); Metal; Group 2 organometallic chemistry; Inorganic chemistry; Combinatorial chemistry; Molecule; Organic chemistry; Mineralogy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002787862,0.0002009336,0.0004119155,0.00002931114,0.00006234312,0.0000543563,0.0001669006,0.0003307705,0.00181085],"category_scores_gemma":[0.0006582452,0.0002230468,0.00005199918,0.0002774427,0.00004211297,0.0001235679,0.00009446596,0.0001782362,0.00001886698],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005557117,"about_ca_system_score_gemma":0.0000796523,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002017347,"about_ca_topic_score_gemma":0.000002689559,"domain_scores_codex":[0.9985154,0.00002538301,0.000570133,0.0004865891,0.0001924628,0.0002099964],"domain_scores_gemma":[0.9987948,0.0001614742,0.00035154,0.0005270331,0.00009818575,0.00006696913],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001680391,0.000102253,0.00002865361,0.0006375326,0.0000284585,0.000002548753,0.00006924856,0.000001407261,0.9976038,0.000523337,0.000008645826,0.0009772531],"study_design_scores_gemma":[0.0002176848,0.000002061075,0.0001928021,0.0003170433,0.00006275006,0.00003742854,0.0001161015,0.00005968135,0.9959888,0.001663449,0.001145327,0.0001968311],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973606,0.0005731266,0.0008697331,0.0001777124,0.00003762463,0.0001257618,0.00006812243,0.0000551135,0.0007321517],"genre_scores_gemma":[0.9968207,0.0002150879,0.002074962,0.00002379053,0.0001402853,0.0001388457,0.0001649109,0.00003536453,0.0003860862],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001791983,"threshold_uncertainty_score":0.9991016,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01305397090796861,"score_gpt":0.2470105662349776,"score_spread":0.2339565953270089,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}