{"id":"W3168869418","doi":"10.1002/chem.202101324","title":"Iron‐Catalyzed Halogen Exchange of Trifluoromethyl Arenes**","year":2021,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Halogen; Catalysis; Chemistry; Reagent; Halide; Trifluoromethyl; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003467124,0.0003107699,0.0002532539,0.0001399336,0.0001124511,0.0001361274,0.0002501479,0.000214916,0.001320399],"category_scores_gemma":[0.000276065,0.0000839428,0.0002131622,0.0001094688,0.0001611149,0.0001530286,0.0001685984,0.0002344685,0.0002133985],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001566152,"about_ca_system_score_gemma":0.0001299007,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004775984,"about_ca_topic_score_gemma":0.0006521257,"domain_scores_codex":[0.9998413,0.00003550291,0.000006808327,0.00003198703,0.00003738065,0.00004688977],"domain_scores_gemma":[0.9998716,0.00003784624,0.00003994456,0.00001643799,0.00001962585,0.00001452993],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002164807,0.00002745453,0.0001371809,0.0001225272,0.00001458507,0.00009949298,0.00003661776,0.0004494517,0.9920781,0.000255383,0.0001333351,0.00642949],"study_design_scores_gemma":[0.00002242335,0.0003288604,0.0004153666,0.000003950724,0.000006965681,0.0000857532,0.00000604669,0.001028368,0.9969096,0.00002689904,0.001160616,0.000005138302],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883194,0.0005650104,0.008133885,0.00004552366,0.00001840893,0.00005415377,0.0001474269,0.0001049715,0.00261123],"genre_scores_gemma":[0.9941648,0.0002481176,0.004215301,0.00001992068,0.00000512114,0.00001758507,0.00009586341,0.00001751574,0.001215798],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001320399,"threshold_uncertainty_score":0.004417121,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08891260193736081,"score_gpt":0.374495288320278,"score_spread":0.2855826863829172,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}