{"id":"W3169139502","doi":"10.1002/anie.202103965","title":"Near‐Infrared‐Emitting Boron‐Difluoride‐Curcuminoid‐Based Polymers Exhibiting Thermally Activated Delayed Fluorescence as Biological Imaging Probes","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":97,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polymer; Photochemistry; Fluorescence; Polymerization; Chemistry; Curcuminoid; Materials science; Hypsochromic shift; Photoluminescence; Organic chemistry; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001858031,0.0004292619,0.0001681357,0.0002101665,0.0001037658,0.0001915777,0.0001585656,0.0002929447,0.001109517],"category_scores_gemma":[0.0001751532,0.0002052494,0.0002117694,0.00009937631,0.0002127579,0.0003236626,0.0001463174,0.0003407414,0.0004622346],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003330206,"about_ca_system_score_gemma":0.0001823485,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002667883,"about_ca_topic_score_gemma":0.0004395623,"domain_scores_codex":[0.9999312,0.00001409703,0.00000321496,0.00001769495,0.00001021423,0.00002355076],"domain_scores_gemma":[0.9998903,0.00002950502,0.0000349618,0.00001030201,0.00001310575,0.00002177479],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003731852,0.000008196876,0.00003617256,0.00003264371,0.000002162529,0.00002120705,0.000007697999,0.0001171271,0.9981938,0.0001209886,0.00002046603,0.00140213],"study_design_scores_gemma":[0.000006546884,0.00006490001,0.0002561204,0.000002732048,0.000004390963,0.00005138108,0.000003223643,0.0003291155,0.9983214,0.00002325335,0.0009328607,0.000004025948],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761848,0.002426913,0.01731936,0.000145969,0.00003114639,0.00005773948,0.0001749626,0.0002471737,0.003411898],"genre_scores_gemma":[0.9816043,0.001175903,0.01407559,0.00005381579,0.000008173316,0.00006204849,0.0001138874,0.0000294431,0.002876763],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001109517,"threshold_uncertainty_score":0.0037117,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01545452219661484,"score_gpt":0.2589702428038179,"score_spread":0.2435157206072031,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}