{"id":"W3170843583","doi":"10.1039/d1ra01873f","title":"Thermal desorption effects on fragment ion production from multi-photon ionized uridine and selected analogues","year":2021,"lang":"en","type":"article","venue":"RSC Advances","topic":"Ion-surface interactions and analysis","field":"Engineering","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Central Institute of Medicinal and Aromatic Plants; Fundação para a Ciência e a Tecnologia; Menzies Centre for Australian Studies, King's College London, University of London; Engineering and Physical Sciences Research Council; Agentúra na Podporu Výskumu a Vývoja; Centre National de la Recherche Scientifique; Universität Potsdam; Ministerstvo školstva, vedy, výskumu a športu Slovenskej republiky; Horizon 2020 Framework Programme; Queen's University Belfast; Ministério da Ciência, Tecnologia e Ensino Superior; Vedecká Grantová Agentúra MŠVVaŠ SR a SAV; Applied Molecular Biosciences Unit; Queen's University; Open University; European Commission; University of Wolverhampton","keywords":"Uridine; Ionization; Ion; Nucleoside; Desorption; Chemistry; Photon; Fragment (logic); Thermal; Photochemistry; Physics; RNA; Physical chemistry; Stereochemistry; Organic chemistry; Biochemistry; Optics; Thermodynamics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003975649,0.0001262475,0.0001531312,0.00006302477,0.00008643511,0.0000355051,0.00002744156,0.00004295523,0.00005172121],"category_scores_gemma":[0.00005408479,0.0001138291,0.00003819098,0.0002577983,0.00001071782,0.0002304338,0.000008985569,0.000112423,0.00002015582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005936213,"about_ca_system_score_gemma":0.000006458525,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000303031,"about_ca_topic_score_gemma":0.0001098297,"domain_scores_codex":[0.9993745,0.00004447711,0.0001304713,0.000224526,0.000103441,0.0001225908],"domain_scores_gemma":[0.9996789,0.00006423999,0.00003353499,0.000117569,0.0000727733,0.00003301996],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002981262,0.0000696424,0.001454184,0.00005067395,0.0001062045,0.00000908634,0.0001504065,0.07009838,0.8967931,0.000006307757,0.00006107268,0.03117111],"study_design_scores_gemma":[0.0003777274,0.0000452641,0.01168047,0.0001367128,0.00005819044,0.000002744572,0.00009544154,0.05228744,0.9329377,0.00004855784,0.002158743,0.0001710111],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926894,0.003172052,0.003159944,0.00009549989,0.0005688589,0.00009727602,0.00000729117,0.0001569587,0.00005271163],"genre_scores_gemma":[0.9951232,0.001659899,0.002725278,0.00001439608,0.0001987493,0.00002360887,0.0001174664,0.00001601789,0.0001213545],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03614457,"threshold_uncertainty_score":0.4641814,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006703689314149376,"score_gpt":0.2270538773045759,"score_spread":0.2203501879904265,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}