{"id":"W3170843583","doi":"10.1039/d1ra01873f","title":"Thermal desorption effects on fragment ion production from multi-photon ionized uridine and selected analogues","year":2021,"lang":"en","type":"article","venue":"RSC Advances","topic":"Ion-surface interactions and analysis","field":"Engineering","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Central Institute of Medicinal and Aromatic Plants; Fundação para a Ciência e a Tecnologia; Menzies Centre for Australian Studies, King's College London, University of London; Engineering and Physical Sciences Research Council; Agentúra na Podporu Výskumu a Vývoja; Centre National de la Recherche Scientifique; Universität Potsdam; Ministerstvo školstva, vedy, výskumu a športu Slovenskej republiky; Horizon 2020 Framework Programme; Queen's University Belfast; Ministério da Ciência, Tecnologia e Ensino Superior; Vedecká Grantová Agentúra MŠVVaŠ SR a SAV; Applied Molecular Biosciences Unit; Queen's University; Open University; European Commission; University of Wolverhampton","keywords":"Uridine; Ionization; Ion; Nucleoside; Desorption; Chemistry; Photon; Fragment (logic); Thermal; Photochemistry; Physics; RNA; Physical chemistry; Stereochemistry; Organic chemistry; Biochemistry; Optics; Thermodynamics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002147278,0.0003101971,0.0002124656,0.000150487,0.0001831504,0.0002327969,0.0002945067,0.0002728265,0.003443392],"category_scores_gemma":[0.0005112608,0.000127416,0.0001685727,0.0001915319,0.0003244006,0.0002698031,0.0002059507,0.0004831004,0.0003038861],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000198281,"about_ca_system_score_gemma":0.0000791391,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000434517,"about_ca_topic_score_gemma":0.0005460516,"domain_scores_codex":[0.9998646,0.00001372234,0.000003506192,0.00003617465,0.00004239895,0.00003960932],"domain_scores_gemma":[0.9997235,0.0001665936,0.00003818043,0.00001934621,0.0000321487,0.00002021047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002805795,0.000008046642,0.0002189592,0.00005599039,0.000004319215,0.00005562316,0.0000713189,0.0001630216,0.9972823,0.00005534852,0.00003361158,0.00177102],"study_design_scores_gemma":[0.000004110398,0.0001090726,0.001754211,0.000002313727,0.000003979491,0.00006581241,0.0000246654,0.0005011648,0.9972098,0.00001749622,0.0003039594,0.000003421831],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947717,0.000678274,0.002345445,0.00003469077,0.00000866135,0.00001140478,0.0002220026,0.00004455657,0.00188326],"genre_scores_gemma":[0.9975283,0.0002724806,0.001058843,0.00001855161,0.000003356466,0.00001224475,0.0001875752,0.00003461035,0.0008841403],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003443392,"threshold_uncertainty_score":0.01151931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006703689314149376,"score_gpt":0.2270538773045759,"score_spread":0.2203501879904265,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}