{"id":"W3171346821","doi":"10.1002/ejoc.202100565","title":"A Highly Congested Dioxapyrenophane from an Attempted Synthesis of the Highly‐Strained 1,1,6,6‐Tetramethyl[6](2,11)teropyrenophane","year":2021,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Steric effects; Ether; Stereochemistry; Substructure; Atom (system on chip); Combinatorial chemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009512447,0.0003105317,0.0001678228,0.0001992798,0.000155905,0.0001351359,0.000217295,0.0002397913,0.00169794],"category_scores_gemma":[0.000112336,0.0001146423,0.0001258736,0.0002147765,0.000133723,0.0002646879,0.0002875049,0.0003502494,0.000456983],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000120081,"about_ca_system_score_gemma":0.0003031028,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002064361,"about_ca_topic_score_gemma":0.0004894161,"domain_scores_codex":[0.9999429,0.00000917441,0.000004555,0.00001075086,0.00001324562,0.00001935424],"domain_scores_gemma":[0.9999639,0.000004504944,0.000007761022,0.000005871421,0.000004671868,0.00001337729],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008566246,0.00004993655,0.0001801846,0.0002240935,0.0000128137,0.0005730118,0.00009628349,0.0006222242,0.9872741,0.001666101,0.0001769852,0.009038655],"study_design_scores_gemma":[0.00005985194,0.001198723,0.002393736,0.00004670805,0.00003362195,0.0008713785,0.00006691628,0.001397414,0.9748081,0.0005913439,0.01851002,0.00002216666],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9773247,0.001267886,0.00975147,0.0001214057,0.00006564838,0.0001113552,0.0006255968,0.0000803283,0.01065153],"genre_scores_gemma":[0.9887379,0.00131469,0.006855566,0.00003152881,0.000008422017,0.00003863731,0.0003900598,0.00001668594,0.002606477],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00169794,"threshold_uncertainty_score":0.005680144,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006587733491943683,"score_gpt":0.2067641290958031,"score_spread":0.2001763956038594,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}