{"id":"W3173173017","doi":"10.1016/j.jhazmat.2021.126411","title":"Kinetic and reaction mechanism of generated by-products in a photocatalytic oxidation reactor: Model development and validation","year":2021,"lang":"en","type":"article","venue":"Journal of Hazardous Materials","topic":"TiO2 Photocatalysis and Solar Cells","field":"Energy","cited_by":28,"is_retracted":false,"has_abstract":false,"ca_institutions":"Health Canada; Concordia University","funders":"","keywords":"Acetaldehyde; Photocatalysis; Chemistry; Acetone; Acetic acid; Formaldehyde; Relative humidity; Ketone; Continuous stirred-tank reactor; Reaction rate; Reaction mechanism; Bromate; Catalysis; Organic chemistry; Ethanol; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006486655,0.000123311,0.0003761193,0.0001459297,0.00002713311,0.00006492098,0.00005235259,0.00008576858,0.00002371224],"category_scores_gemma":[0.00009555781,0.0001125047,0.00002226396,0.0001351356,0.0000137801,0.0002198727,0.00003197247,0.00006419191,0.00000200645],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006786006,"about_ca_system_score_gemma":0.0001251743,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001040672,"about_ca_topic_score_gemma":0.00003323012,"domain_scores_codex":[0.9986191,0.0001107472,0.0007633318,0.0001743453,0.0002160041,0.0001164592],"domain_scores_gemma":[0.999015,0.00002006532,0.0005414989,0.0001341624,0.0002397985,0.00004943106],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007670713,0.00007701873,0.00001188293,0.0000745084,0.0000413744,0.00001305608,0.0004551978,0.0001789073,0.9979618,0.0003106109,0.00004976602,0.0007491946],"study_design_scores_gemma":[0.0006237937,0.00004578706,0.0002112423,0.00007162565,0.00005372614,0.00009781221,0.00008535037,0.0005252549,0.9971702,0.0006465699,0.000360919,0.0001077935],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990087,0.0002348463,0.0003423425,0.00005571494,0.0001574251,0.0001191964,0.000005606178,0.000005329072,0.00007088603],"genre_scores_gemma":[0.9970464,0.0002995362,0.002392068,0.00001902387,0.0000449238,0.000005402,0.00007096505,0.00001687079,0.0001047974],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002049726,"threshold_uncertainty_score":0.4587808,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02009714649176512,"score_gpt":0.2273434338491797,"score_spread":0.2072462873574145,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}