{"id":"W3173704137","doi":"10.1039/d1sc03076k","title":"Synthesis and enantioseparation of chiral Au<sub>13</sub> nanoclusters protected by bis-<i>N</i>-heterocyclic carbene ligands","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Queen's University; Canada Foundation for Innovation; Japan Society for the Promotion of Science; Mazda Foundation","keywords":"Nanoclusters; Carbene; Halide; Chemistry; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003582589,0.0001603854,0.0002589077,0.00005771064,0.0002494028,0.0001281954,0.0003999663,0.00008461913,0.0000251858],"category_scores_gemma":[0.0003779265,0.0001370234,0.00005384318,0.0006997254,0.0007485377,0.0003131496,0.0002380777,0.00007347237,0.00001286748],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008073768,"about_ca_system_score_gemma":0.000187112,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000357088,"about_ca_topic_score_gemma":0.0000113468,"domain_scores_codex":[0.9981616,0.00003086808,0.0003508643,0.0006195267,0.0004356522,0.0004014972],"domain_scores_gemma":[0.9990003,0.000131291,0.0001615956,0.0003815185,0.0001379973,0.0001873369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008486298,0.00006494798,0.0001361029,0.00002943975,0.000002226683,7.427276e-7,0.0001090548,0.000001927601,0.9971759,0.00007378539,0.00009590844,0.002301535],"study_design_scores_gemma":[0.0001387201,0.00001523991,0.0005571354,0.00006132699,0.00001732216,0.00001493527,0.00003285444,0.000239008,0.9985136,0.00009499874,0.0001419924,0.0001728412],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998183,0.0001263029,0.000466173,0.0003960291,0.00008604611,0.0002027354,0.00003601913,0.000046786,0.0004569081],"genre_scores_gemma":[0.9988088,0.0000284835,0.0009029577,0.00006878436,0.00004226877,0.00009479405,0.000004883621,0.00001028202,0.00003872832],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002128694,"threshold_uncertainty_score":0.5587651,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007721243070137314,"score_gpt":0.2237566773210078,"score_spread":0.2160354342508705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}