{"id":"W3174290187","doi":"10.1021/acs.macromol.1c00746","title":"High-Sensitivity Microcalorimetry and Gel Permeation Chromatography in Tandem Reveal the Complexity of the Synthesis of Poly-(2-isopropyl-2-oxazoline) Stars","year":2021,"lang":"en","type":"article","venue":"Macromolecules","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Gel permeation chromatography; Isopropyl; Isothermal microcalorimetry; Oxazoline; Chemistry; Tandem; Permeation; Chromatography; Polymer chemistry; Polymer; Organic chemistry; Materials science; Membrane; Thermodynamics; Enthalpy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002035702,0.0001962139,0.0003879687,0.00004060644,0.0001140043,0.00002170255,0.0001992272,0.0001439993,0.00008214128],"category_scores_gemma":[0.0001791735,0.000137402,0.0002410512,0.0005308411,0.001142276,0.00003588667,0.0001742061,0.00024575,5.634427e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002121172,"about_ca_system_score_gemma":0.00005680009,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003188818,"about_ca_topic_score_gemma":0.0001200754,"domain_scores_codex":[0.9986436,0.0001137423,0.0004179484,0.0003066867,0.0002895455,0.0002285182],"domain_scores_gemma":[0.9988953,0.0002526738,0.0002081598,0.0004799379,0.0001090745,0.00005483503],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002258336,0.0001351887,0.07531931,0.0003449322,0.0001025089,0.00002786041,0.0001044481,0.000002303526,0.9223473,0.001175289,0.00004472025,0.0003735638],"study_design_scores_gemma":[0.000243916,0.000005773314,0.07916789,0.0002121097,0.00009065963,0.00004879176,0.0005572797,0.0001374845,0.9176983,0.00167625,0.00002382255,0.0001377253],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970053,0.0009652665,0.0001106731,0.0004332323,0.00002093071,0.00005361333,0.0001204235,0.00001735356,0.001273201],"genre_scores_gemma":[0.9992957,0.00006052582,0.0004818843,0.00005744157,0.00003296445,0.00000594371,0.00001788792,0.00001574081,0.000031945],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004648989,"threshold_uncertainty_score":0.5603091,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0123937684351025,"score_gpt":0.2189312586035191,"score_spread":0.2065374901684166,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}