{"id":"W3174454982","doi":"10.33774/chemrxiv-2021-tm4gl-v2","title":"Highly optically responsive divalent benzimidazolium-based axles as self-reporting pseudorotaxanes","year":2021,"lang":"en","type":"preprint","venue":"","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund; Compute Canada","keywords":"Axle; Protonation; Chemistry; Spectroscopy; Divalent; Quenching (fluorescence); Solvent; Mass spectrometry; Chemical physics; Photochemistry; Fluorescence; Organic chemistry; Chromatography; Physics; Thermodynamics; Optics; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004509659,0.0009403521,0.001089191,0.00008617083,0.0002422615,0.0005763578,0.001009475,0.00103968,0.008132995],"category_scores_gemma":[0.002477388,0.0009677538,0.0009262227,0.0001595269,0.0001468074,0.00007068156,0.001733979,0.001482547,0.00006509718],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002621119,"about_ca_system_score_gemma":0.001643436,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002207507,"about_ca_topic_score_gemma":0.00001643393,"domain_scores_codex":[0.9943521,0.00009936125,0.00196955,0.001751292,0.001024757,0.0008029189],"domain_scores_gemma":[0.9945381,0.0004922873,0.001752735,0.002212147,0.0005936646,0.0004110264],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003448123,0.001034557,0.003264096,0.004680661,0.001436401,0.006059761,0.0005969855,0.003330829,0.9770878,0.0006385451,0.0005714885,0.0009540734],"study_design_scores_gemma":[0.000544471,0.00002123684,0.0001621668,0.0008341937,0.0003891772,0.0002604122,0.00112753,0.001494355,0.9915072,0.0006052643,0.001827783,0.00122626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9257887,0.0006881676,0.0006072047,0.0008829717,0.00027925,0.0001939392,0.00004262616,0.0009830883,0.07053403],"genre_scores_gemma":[0.9763467,0.00005705001,0.01907375,0.0004406064,0.0005289363,0.0002410995,0.0007814965,0.0001317664,0.00239859],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06813544,"threshold_uncertainty_score":0.9992773,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02421670314162922,"score_gpt":0.2785854302394942,"score_spread":0.254368727097865,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}