{"id":"W3177168995","doi":"10.1039/d1nj02298a","title":"Reactivity of 1,3-dichloro-1,3-bis(dimethylamino)-propenium salts with primary amines","year":2021,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Primary (astronomy); Reactivity (psychology); Amine gas treating; Medicinal chemistry; Hydrogen; Organic chemistry; Carbon fibers; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005311926,0.000698065,0.0004618983,0.0002759589,0.0002519692,0.0002526404,0.0004754172,0.000912722,0.00260019],"category_scores_gemma":[0.0008229066,0.0002620409,0.0003854171,0.0001976946,0.0003324746,0.000341796,0.0002356253,0.0005484259,0.0008341841],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003182743,"about_ca_system_score_gemma":0.0002066188,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005937727,"about_ca_topic_score_gemma":0.0008830085,"domain_scores_codex":[0.9994843,0.0001349372,0.00002988099,0.00009210191,0.0001064531,0.0001522734],"domain_scores_gemma":[0.9994678,0.0002069776,0.0001061243,0.00004718576,0.00007596677,0.00009583933],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003483865,0.00001997568,0.0002017508,0.0001154603,0.00001711053,0.0001821373,0.00005041492,0.000124427,0.9977654,0.00008704115,0.00008060953,0.001007169],"study_design_scores_gemma":[0.00001366462,0.0003663665,0.0005332401,0.000005526467,0.000008115482,0.0001499938,0.00000992751,0.0001942431,0.9980926,0.00001577145,0.0006055341,0.000005030269],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9888393,0.002625428,0.002364684,0.0001255723,0.0001077054,0.00007162966,0.0002065008,0.00008244807,0.005576598],"genre_scores_gemma":[0.9922758,0.001366724,0.00189486,0.00006006099,0.00003823276,0.00003458126,0.0003813537,0.00003740638,0.003911118],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00260019,"threshold_uncertainty_score":0.008698523,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05148134189684344,"score_gpt":0.3618027143666021,"score_spread":0.3103213724697586,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}