{"id":"W3178861200","doi":"10.1515/pac-2021-0110","title":"The exploration of deoxygenation reactions for alcohols and derivatives using earth-abundant reagents","year":2021,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Deoxygenation; Chemistry; Earth (classical element); Reagent; Rare earth; Astrobiology; Process (computing); Earth science; Organic chemistry; Catalysis; Geology; Mineralogy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005033104,0.0005658311,0.0002759921,0.0003857086,0.0002559393,0.000408532,0.000364226,0.0004791332,0.002670272],"category_scores_gemma":[0.0003733941,0.0001841747,0.0004334432,0.0004586606,0.0003738142,0.001290988,0.0005694746,0.001048132,0.0008317719],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003718077,"about_ca_system_score_gemma":0.0003144742,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004163943,"about_ca_topic_score_gemma":0.0006313021,"domain_scores_codex":[0.9998372,0.00003329493,0.00001039382,0.00003516526,0.00004488634,0.00003910425],"domain_scores_gemma":[0.9999027,0.0000333062,0.0000143776,0.00001282769,0.00002470598,0.00001206655],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003874619,0.0003910115,0.001385428,0.008385424,0.0001819951,0.00146895,0.000673628,0.005059221,0.70701,0.08072578,0.009203137,0.1851281],"study_design_scores_gemma":[0.00004339953,0.001057412,0.0009707739,0.0002843523,0.00008298866,0.0007994043,0.0001749131,0.003476108,0.7886269,0.009127899,0.19529,0.00006580305],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4086069,0.4069503,0.07722659,0.003362688,0.001509942,0.0002612823,0.0008958224,0.0002971985,0.1008894],"genre_scores_gemma":[0.853887,0.1260589,0.01121351,0.0006839187,0.000189391,0.00006583894,0.0003693161,0.000061865,0.007470211],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002670272,"threshold_uncertainty_score":0.008932889,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03262074918751686,"score_gpt":0.2685339333033698,"score_spread":0.2359131841158529,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}