{"id":"W3184964380","doi":"10.1021/acs.joc.1c00995","title":"Chiral Benzothiazole Monofluoroborate Featuring Chiroptical and Oxygen-Sensitizing Properties: Synthesis and Photophysical Studies","year":2021,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"H2020 European Research Council; Région Bretagne; Université Toulouse III - Paul Sabatier; Agence Nationale de la Recherche","keywords":"Benzothiazole; Chemistry; Singlet oxygen; Stereocenter; Photodynamic therapy; Enantiomer; BODIPY; Combinatorial chemistry; Molecule; Photosensitizer; Nanotechnology; Oxygen; Photochemistry; Fluorescence; Stereochemistry; Enantioselective synthesis; Organic chemistry; Materials science; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001373444,0.0001843691,0.0001179704,0.0001779103,0.00016379,0.0001535684,0.0001749691,0.0002139602,0.000662252],"category_scores_gemma":[0.0001629105,0.00009588511,0.00007495294,0.0001930303,0.0001899859,0.0001460425,0.00008665842,0.0002209354,0.0001486177],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005184621,"about_ca_system_score_gemma":0.0002752455,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002353316,"about_ca_topic_score_gemma":0.002832878,"domain_scores_codex":[0.9999278,0.00001191724,0.000004381028,0.00001132462,0.00002617348,0.00001836939],"domain_scores_gemma":[0.9999455,0.000007409517,0.00002063728,0.000004017742,0.000008846052,0.00001359057],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005967802,0.00004207656,0.00009826995,0.00011245,0.000003378698,0.0000753252,0.00003853176,0.0004987134,0.9940767,0.001072824,0.00008271688,0.003839194],"study_design_scores_gemma":[0.00001232784,0.0002021764,0.0004847647,0.00000521903,0.000004542695,0.0001356889,0.00001070277,0.00109125,0.9950528,0.00004513699,0.002948827,0.000006668242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9808362,0.004754838,0.006135772,0.0002340342,0.00002532283,0.00006378253,0.0001757549,0.00004893712,0.007725397],"genre_scores_gemma":[0.9915165,0.002460965,0.004466402,0.00003086462,0.00001299299,0.00001637236,0.00009335136,0.000008512307,0.001394094],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002353316,"threshold_uncertainty_score":0.004679203,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02157528657911502,"score_gpt":0.2317943168091325,"score_spread":0.2102190302300175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}