{"id":"W3186474674","doi":"10.1021/acs.inorgchem.1c00801","title":"Trans Element-Hydrogen Bonds: A Distinctive Difference Between Transition Metals and Main Group Elements","year":2021,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Hydride; Porphyrin; Group (periodic table); Crystallography; Antisymmetric relation; Triatomic molecule; Main group element; Singlet state; Transition metal; Hydrogen; Hydrogen bond; Atomic physics; Stereochemistry; Molecule; Photochemistry; Excited state; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000331564,0.0002558169,0.0003971736,0.00001469088,0.0001510726,0.0001152362,0.0001957303,0.0001378999,0.00349636],"category_scores_gemma":[0.00004635416,0.0002562179,0.00006097432,0.0001345975,0.00008918471,0.0001386146,0.00009312075,0.000107388,0.00002959064],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008809707,"about_ca_system_score_gemma":0.0000797166,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003553856,"about_ca_topic_score_gemma":0.00001955989,"domain_scores_codex":[0.9981613,0.00009278079,0.0004700329,0.0005741878,0.0002966797,0.0004050082],"domain_scores_gemma":[0.9992684,0.00005437916,0.0001239984,0.0003212228,0.00004976925,0.0001822899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001360856,0.00006663497,0.0002057829,0.0001389443,0.00004880219,0.00007228518,0.0005096907,7.622565e-7,0.9986063,0.00001046151,0.00003763581,0.0002890879],"study_design_scores_gemma":[0.0006656505,0.00002790672,0.0004244895,0.00004267832,0.0001523843,0.00006499934,0.0002199676,0.00001255544,0.996749,0.0005213913,0.0008317581,0.0002872575],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956411,0.0002747444,0.002628912,0.0001467602,0.00005328901,0.0001517854,0.0008053516,0.00008125417,0.0002168753],"genre_scores_gemma":[0.9986171,0.00004018065,0.0003385236,0.0001148992,0.0002046156,0.00003511094,0.0002777748,0.00002923807,0.0003425893],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00346677,"threshold_uncertainty_score":0.999989,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01165658230613861,"score_gpt":0.2312732041544667,"score_spread":0.2196166218483281,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}