{"id":"W3188360837","doi":"10.1002/anie.202109345","title":"Can One Measure Resonance Raman Optical Activity?","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Compute Canada; Canada Foundation for Innovation; University of Alberta; Ministry of Innovation and Advanced Education","keywords":"Raman spectroscopy; Raman optical activity; Resonance (particle physics); Resonance Raman spectroscopy; Coherent anti-Stokes Raman spectroscopy; Spectroscopy; Raman scattering; Chemistry; Molecular physics; Circular dichroism; Nuclear magnetic resonance; Circular polarization; Analytical Chemistry (journal); Optics; Atomic physics; Physics; Crystallography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008399336,0.0001397656,0.0001413813,0.00002307539,0.00007564391,0.00007521969,0.0001834396,0.0001465822,0.003262426],"category_scores_gemma":[0.0002125443,0.0001619851,0.0001153128,0.00008464597,0.00005755373,0.0001469805,0.0000706926,0.0003006411,0.00002628599],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002126286,"about_ca_system_score_gemma":0.00009821777,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003097505,"about_ca_topic_score_gemma":0.00006188614,"domain_scores_codex":[0.9987122,0.00001182014,0.0001671896,0.0003599656,0.0005488647,0.0001999054],"domain_scores_gemma":[0.9992934,0.00003638591,0.00007579189,0.000261411,0.0002386783,0.00009428478],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006408308,0.0002255862,0.000370999,0.0000299486,0.00006734083,0.00007058791,0.00005387122,0.000001519882,0.9913343,0.002827908,0.002924623,0.002029264],"study_design_scores_gemma":[0.0004784189,0.000007748936,0.001099733,0.00009569403,0.00002302154,0.00003126149,0.00002365258,0.00002631165,0.9763907,0.001761278,0.01989486,0.0001673387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5900874,0.0005130383,0.006261085,0.01802387,0.001363179,0.00007317627,0.0004055078,0.0002355591,0.3830372],"genre_scores_gemma":[0.9937819,0.00007773304,0.0005263987,0.0004202271,0.001769922,0.00002734083,0.0006136915,0.00001857843,0.002764205],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4036945,"threshold_uncertainty_score":0.9976487,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01744658234929598,"score_gpt":0.2628207887259323,"score_spread":0.2453742063766363,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}