{"id":"W3188360837","doi":"10.1002/anie.202109345","title":"Can One Measure Resonance Raman Optical Activity?","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Compute Canada; Canada Foundation for Innovation; University of Alberta; Ministry of Innovation and Advanced Education","keywords":"Raman spectroscopy; Raman optical activity; Resonance (particle physics); Resonance Raman spectroscopy; Coherent anti-Stokes Raman spectroscopy; Spectroscopy; Raman scattering; Chemistry; Molecular physics; Circular dichroism; Nuclear magnetic resonance; Circular polarization; Analytical Chemistry (journal); Optics; Atomic physics; Physics; Crystallography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.004203405,0.001332858,0.001357253,0.001507924,0.0004501032,0.002396682,0.001722911,0.00314329,0.002931156],"category_scores_gemma":[0.01306657,0.0006725201,0.0005081182,0.0009227153,0.00325328,0.006404892,0.001281694,0.002591033,0.001505103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006815536,"about_ca_system_score_gemma":0.0003957002,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003600617,"about_ca_topic_score_gemma":0.0003096682,"domain_scores_codex":[0.9974754,0.0009991728,0.00006943275,0.0006323256,0.0006517746,0.000171826],"domain_scores_gemma":[0.9955171,0.00259722,0.0004965764,0.0005793269,0.0006040603,0.0002058383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006001811,0.0007153018,0.02043216,0.002861037,0.0005519017,0.0004587969,0.000684129,0.006794311,0.4784076,0.2034734,0.0103978,0.2746234],"study_design_scores_gemma":[0.0001029328,0.0009751267,0.008025768,0.0007829854,0.0002777361,0.001452519,0.001745705,0.06051109,0.4754351,0.405089,0.04499352,0.0006084474],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.2315824,0.05458222,0.6309469,0.03210615,0.006108798,0.0001820769,0.000727759,0.002214426,0.04154922],"genre_scores_gemma":[0.8814022,0.01270151,0.09585387,0.003434071,0.001117638,0.0002233831,0.0002403875,0.0001767707,0.004850227],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.004203405,"threshold_uncertainty_score":0.02223003,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01744658234929598,"score_gpt":0.2628207887259323,"score_spread":0.2453742063766363,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}