{"id":"W3189743207","doi":"10.33774/chemrxiv-2021-mwk57","title":"A monoanionic pentadentate ligand platform for scandium-pnictogen multiple bonds","year":2021,"lang":"en","type":"preprint","venue":"","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Innovates; Chinese Academy of Sciences; Alexander von Humboldt-Stiftung; Institut Universitaire de France; Canada Research Chairs; Alberta Innovates - Technology Futures","keywords":"Pnictogen; Phosphinidene; Ligand (biochemistry); Scandium; Chemistry; Yield (engineering); Cleavage (geology); Bond; Bond cleavage; Crystallography; Stereochemistry; Materials science; Organic chemistry; Business; Physics; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007277379,0.0003186031,0.000164953,0.0001688521,0.0002062391,0.0003793573,0.0003863928,0.0002280872,0.003018582],"category_scores_gemma":[0.00006688954,0.0001640003,0.0001159186,0.0001826316,0.0001497496,0.0003204479,0.0005181286,0.00039005,0.001021662],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003118407,"about_ca_system_score_gemma":0.0002063947,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003480782,"about_ca_topic_score_gemma":0.000610291,"domain_scores_codex":[0.9999288,0.000006006149,0.000004611482,0.00001900772,0.00002207318,0.00001948332],"domain_scores_gemma":[0.9999659,0.000003065234,0.000007858748,0.000006348417,0.000003726874,0.00001306112],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001824647,0.00004399135,0.0001388641,0.0001611594,0.000008464603,0.0001951071,0.00004715777,0.0006959275,0.9772549,0.006288306,0.0009044768,0.01407905],"study_design_scores_gemma":[0.00004196983,0.0004603823,0.0003675053,0.000008360984,0.00001045025,0.000297982,0.00002155384,0.002213378,0.9707811,0.000412363,0.02536745,0.00001751838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.940285,0.001614637,0.02528114,0.0002778545,0.000160895,0.00009352052,0.0005654588,0.0005939032,0.03112775],"genre_scores_gemma":[0.974449,0.0008827447,0.0133805,0.00009090288,0.00002329781,0.00007330329,0.0004537483,0.00007270345,0.01057366],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003018582,"threshold_uncertainty_score":0.01009816,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02747718274523526,"score_gpt":0.2709430422218979,"score_spread":0.2434658594766627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}