{"id":"W3191095354","doi":"10.1016/j.ccr.2021.214127","title":"Enhancing the photophysical properties of Ru(II) complexes by specific design of tridentate ligands","year":2021,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":56,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Deutscher Akademischer Austauschdienst; Compute Canada","keywords":"Chemistry; Artificial photosynthesis; Electrochemistry; Photosensitizer; Combinatorial chemistry; Photochemistry; Terpyridine; Metal ions in aqueous solution; Bipyridine; Ruthenium; Metal; Ligand (biochemistry); Catalysis; Redox; Photocatalysis; Organic chemistry; Crystal structure; Receptor; Physical chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002811119,0.0004242322,0.0004508825,0.0001937042,0.0001615611,0.000664057,0.0006472496,0.0005005827,0.001563658],"category_scores_gemma":[0.0002333714,0.00023237,0.000208644,0.0001928791,0.0002724121,0.0004075308,0.0004750652,0.000682727,0.0004784407],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005268357,"about_ca_system_score_gemma":0.0001659261,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002901279,"about_ca_topic_score_gemma":0.0004087546,"domain_scores_codex":[0.9998479,0.00003209816,0.00001211341,0.00004685602,0.00002481714,0.00003618854],"domain_scores_gemma":[0.9999321,0.00001669988,0.00001911205,0.000009380469,0.00001261031,0.00001012314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001275005,0.00005794501,0.00007510708,0.0005128058,0.00002084803,0.0000832618,0.00006315458,0.0008229538,0.9744788,0.003111063,0.0005122776,0.02013423],"study_design_scores_gemma":[0.00002998344,0.000217814,0.000193031,0.00002708629,0.00002735455,0.0001743705,0.00002764842,0.002219058,0.9782151,0.000242582,0.01861103,0.00001489192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8279455,0.0560636,0.08686107,0.001621243,0.0003076586,0.0002967399,0.0002275052,0.0008888798,0.02578784],"genre_scores_gemma":[0.9330279,0.02518939,0.03136776,0.0005787743,0.00005725392,0.0001928809,0.0002565786,0.0001428625,0.009186562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001563658,"threshold_uncertainty_score":0.005230963,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0974343358464308,"score_gpt":0.2846166106827981,"score_spread":0.1871822748363673,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}