{"id":"W3192678361","doi":"10.26434/chemrxiv.8279432.v1","title":"Catalytic Oxidative Benzylation of Amines Enabled by Direct Ionic Decarboxylation","year":2019,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Decarboxylation; Chemistry; Nucleophile; Alkylation; Catalysis; Oxidative decarboxylation; Oxidative phosphorylation; Ionic liquid; Combinatorial chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002049031,0.0005771514,0.0002858799,0.0001860018,0.0001754102,0.0002957374,0.0005577828,0.000381256,0.00359343],"category_scores_gemma":[0.0002384849,0.0001870606,0.0002693225,0.0001817533,0.0003320194,0.0005228886,0.0007799051,0.00102427,0.002151467],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002363575,"about_ca_system_score_gemma":0.0002319932,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002248837,"about_ca_topic_score_gemma":0.0003853337,"domain_scores_codex":[0.9998142,0.00001445821,0.00001704964,0.00004830609,0.00004992884,0.00005607967],"domain_scores_gemma":[0.9998877,0.00001715944,0.00003148345,0.00002908768,0.00001657239,0.00001798909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001432528,0.00007738942,0.0002460571,0.0005066373,0.0000310155,0.00031017,0.0001210089,0.0003131156,0.9723293,0.003711546,0.0006501892,0.02156021],"study_design_scores_gemma":[0.00001390962,0.0001405198,0.0002031893,0.000006771162,0.00001120241,0.0002441732,0.000009208788,0.0003741813,0.9890001,0.0001980424,0.009788669,0.00001000909],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8111382,0.01041018,0.1056538,0.0008032128,0.0006201165,0.0002043351,0.00120496,0.001069964,0.06889528],"genre_scores_gemma":[0.9741366,0.004199802,0.01356016,0.0001517718,0.00008740892,0.00004943269,0.0005049901,0.0001610111,0.007148755],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00359343,"threshold_uncertainty_score":0.01202124,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01125177675465415,"score_gpt":0.2384886103588728,"score_spread":0.2272368336042186,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}