{"id":"W3193854877","doi":"10.1021/acs.chemrev.1c00278","title":"Molecular Main Group Metal Hydrides","year":2021,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":286,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Group (periodic table); Reactivity (psychology); Main group element; Metal; Nanotechnology; Combinatorial chemistry; Catalysis; Organic chemistry; Transition metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004819811,0.0007347759,0.004100553,0.0001246822,0.00004124287,0.00006555831,0.0007922372,0.0006273069,0.00413647],"category_scores_gemma":[0.001482995,0.0005718322,0.003461715,0.001201027,0.00007535941,0.00005277644,0.0003138892,0.0007604725,0.001091209],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002842319,"about_ca_system_score_gemma":0.0001259716,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002012152,"about_ca_topic_score_gemma":2.235597e-7,"domain_scores_codex":[0.9965671,0.0001137907,0.001507957,0.0009214943,0.0004528345,0.0004367866],"domain_scores_gemma":[0.9976017,0.0002054028,0.0006528683,0.001184553,0.00004241607,0.0003130076],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[2.328531e-7,0.00006438005,3.857955e-8,0.01763086,0.0002713464,0.00007332083,0.000003221912,1.177313e-8,0.001148125,0.0002513684,0.003048297,0.9775088],"study_design_scores_gemma":[0.00007463978,0.00000151371,5.874101e-10,0.008263113,0.002312933,0.0000924274,0.000003286774,0.000001933743,0.005086941,0.00001944528,0.9835867,0.000557039],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.000003276389,0.9776493,0.0001141656,0.00001170448,0.00005875356,0.0002399348,0.00005488654,0.00007244614,0.02179555],"genre_scores_gemma":[0.000003283128,0.99431,0.0004211048,0.0001349538,0.0002607228,0.0004021488,0.002732884,0.0001022343,0.001632717],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9805384,"threshold_uncertainty_score":0.9996865,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04504992644241946,"score_gpt":0.3303280334465179,"score_spread":0.2852781070040984,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}