{"id":"W3195369999","doi":"10.1039/d1ce00829c","title":"Schiff base ligands derived from 1,2-bis(2′-nitro-/amino-phenoxy)-3-R-benzene and 2-hydroxy-1-naphthaldehyde and their Cu/Zn(<scp>ii</scp>) complexes: synthesis, characterization, X-ray structures and computational studies","year":2021,"lang":"en","type":"article","venue":"CrystEngComm","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"University of Isfahan; Alexander von Humboldt-Stiftung","keywords":"Schiff base; Nitro; Benzene; Chemistry; X-ray; Base (topology); Stereochemistry; Medicinal chemistry; Crystallography; Polymer chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000910766,0.0001749064,0.0001872665,0.0001154311,0.0001678748,0.0002533643,0.0004368773,0.0001719951,0.002063247],"category_scores_gemma":[0.0001504961,0.0001262642,0.00007076265,0.0002231103,0.00009612441,0.0001491053,0.0001379969,0.0002851866,0.0003341817],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004968411,"about_ca_system_score_gemma":0.0002767071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003320668,"about_ca_topic_score_gemma":0.004034688,"domain_scores_codex":[0.9999642,0.0000074008,0.000001664701,0.000006612646,0.00001196222,0.000008138395],"domain_scores_gemma":[0.999966,0.000008358315,0.00000807976,0.000002662583,0.000007982065,0.00000690187],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002273897,0.0003254525,0.003000118,0.001344161,0.00008567783,0.0003912149,0.0001820185,0.03433559,0.9015437,0.01146526,0.00606803,0.03898495],"study_design_scores_gemma":[0.0002612262,0.0008802384,0.001895512,0.00002961157,0.00004875381,0.000177962,0.0001785551,0.07578888,0.9015099,0.0005582363,0.01863445,0.00003668763],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916404,0.001112268,0.002538818,0.000091596,0.00001435838,0.00003151166,0.0006375021,0.0001220248,0.003811395],"genre_scores_gemma":[0.9916024,0.00067765,0.004349247,0.00002313251,0.000003146269,0.00003705361,0.0009649755,0.0000233691,0.002319047],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003320668,"threshold_uncertainty_score":0.006902218,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04543081572629911,"score_gpt":0.2575148750354279,"score_spread":0.2120840593091287,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}