{"id":"W3195369999","doi":"10.1039/d1ce00829c","title":"Schiff base ligands derived from 1,2-bis(2′-nitro-/amino-phenoxy)-3-R-benzene and 2-hydroxy-1-naphthaldehyde and their Cu/Zn(<scp>ii</scp>) complexes: synthesis, characterization, X-ray structures and computational studies","year":2021,"lang":"en","type":"article","venue":"CrystEngComm","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"University of Isfahan; Alexander von Humboldt-Stiftung","keywords":"Schiff base; Nitro; Benzene; Chemistry; X-ray; Base (topology); Stereochemistry; Medicinal chemistry; Crystallography; Polymer chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003188135,0.0005635986,0.001203076,0.000181427,0.0008166262,0.0002370026,0.000146773,0.0001638392,0.00005558577],"category_scores_gemma":[0.001061371,0.0004164062,0.000114015,0.0002195953,0.0005009169,0.0002565118,0.0004381732,0.0002936979,0.000002944995],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003533799,"about_ca_system_score_gemma":0.0001127586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003973496,"about_ca_topic_score_gemma":0.00002466334,"domain_scores_codex":[0.9974874,0.0002893796,0.0006581895,0.0007925717,0.0003539084,0.0004185685],"domain_scores_gemma":[0.9968778,0.001673786,0.0002470843,0.0004702718,0.0004051485,0.0003259083],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00008851943,0.0001609369,0.01265414,0.0006456339,0.0009909812,0.00005198286,0.005727745,0.00002168617,0.9743738,0.0006185108,0.0003220423,0.004343979],"study_design_scores_gemma":[0.003791773,0.0005832329,0.5862694,0.001655679,0.0009980322,0.0007444292,0.01654594,0.008556944,0.3611542,0.005800757,0.01308136,0.0008182191],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9700658,0.02693508,0.0004575819,0.001333417,0.0001649256,0.0003944502,0.0003080787,0.0001071995,0.0002335029],"genre_scores_gemma":[0.9926089,0.001782164,0.00356377,0.0009639437,0.0002945219,0.00005063038,0.0003590763,0.00007074817,0.0003062446],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6132196,"threshold_uncertainty_score":0.9998288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04543081572629911,"score_gpt":0.2575148750354279,"score_spread":0.2120840593091287,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}