{"id":"W3196585026","doi":"10.3390/molecules26175266","title":"On the Origins of Some Spectroscopic Properties of “Purple Iron” (the Tetraoxoferrate(VI) Ion) and Its Pourbaix Safe-Space","year":2021,"lang":"en","type":"review","venue":"Molecules","topic":"Advanced oxidation water treatment","field":"Environmental Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Compendium; Raman spectroscopy; Pourbaix diagram; Decomposition; Absorbance; Chemistry; Rayleigh scattering; Field (mathematics); Inorganic chemistry; Physical chemistry; Physics; Optics; Mathematics; Organic chemistry; Philosophy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001029614,0.0002879038,0.0005853184,0.00003223256,0.0001009449,0.00001901872,0.0003106182,0.00007353799,0.0004530268],"category_scores_gemma":[0.00005297092,0.0001376482,0.0001346585,0.000186505,0.0002354,0.00007374364,0.000202444,0.0001640466,0.0001395906],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002359256,"about_ca_system_score_gemma":0.00003984549,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005243506,"about_ca_topic_score_gemma":0.00001212028,"domain_scores_codex":[0.9986224,0.0001959852,0.0003296111,0.0003384879,0.0003168988,0.0001966472],"domain_scores_gemma":[0.9991543,0.00007401211,0.0002720528,0.0004492163,0.00001071464,0.00003965568],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001079977,0.00302274,0.0003114674,0.02527864,0.001981158,0.0001951332,0.005594234,0.003827542,0.08909236,0.3704061,0.007006727,0.4931759],"study_design_scores_gemma":[0.0003427597,0.0003187174,0.0001135144,0.00664886,0.0005989868,0.00002349014,0.0001863389,0.00004486544,0.09658762,0.001161109,0.893378,0.0005957228],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0140964,0.9835044,0.00003962205,0.0006750968,0.00007679613,0.0008802841,0.00002615955,0.00001228407,0.0006889693],"genre_scores_gemma":[0.01226609,0.9843593,0.0002717699,0.00007364262,0.00002659505,0.0001184482,0.0000194282,0.00003825554,0.002826417],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8863713,"threshold_uncertainty_score":0.561313,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03314370706601664,"score_gpt":0.2695283184903401,"score_spread":0.2363846114243235,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}