{"id":"W3196591097","doi":"10.1021/acs.jced.1c00352","title":"Standard Partial Molar Heat Capacities and Volumes of Aqueous <i>N</i>,<i>N</i>-Dimethylethanolamine and <i>N</i>,<i>N</i>-Dimethylethanolammonium Chloride from 283.15 to 393.15 K, and Ionization Constants to 598.15 K","year":2021,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada; University Network of Excellence in Nuclear Engineering","keywords":"Aqueous solution; Chemistry; Chloride; Molar; Nuclear chemistry; Physical chemistry; Organic chemistry; Geology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005693474,0.000533274,0.001154652,0.0002200751,0.00005543436,0.0001251439,0.0006772918,0.0002953302,0.00004234468],"category_scores_gemma":[0.002217002,0.000516539,0.00009079767,0.0003714758,0.0001961674,0.0005743438,0.001119014,0.0007374892,0.000002075149],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001242658,"about_ca_system_score_gemma":0.0001247071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001007403,"about_ca_topic_score_gemma":0.000008537132,"domain_scores_codex":[0.9968415,0.00005590016,0.001124219,0.0006837313,0.0007172003,0.0005774034],"domain_scores_gemma":[0.997382,0.0005047481,0.000218251,0.0008540152,0.0003783996,0.0006625464],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005181257,0.00004877341,0.0001749636,0.0002308081,0.0002800087,0.00008937823,0.0005858201,0.001756216,0.9932021,0.00005051619,0.000651808,0.002411421],"study_design_scores_gemma":[0.001378298,0.0001549214,0.00007931741,0.0007206526,0.0002065994,0.0003003467,0.0001579097,0.01459564,0.9769629,0.00007989096,0.004798621,0.0005648963],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9615191,0.01315025,0.0226291,0.0008425077,0.0003987263,0.0002258107,0.001125925,0.00008478693,0.00002375688],"genre_scores_gemma":[0.9760757,0.0005593135,0.02234072,0.0002763727,0.0004592806,0.000007712813,0.0001381827,0.0001118775,0.00003083277],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01623925,"threshold_uncertainty_score":0.9997286,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01223998423040087,"score_gpt":0.2226759576330087,"score_spread":0.2104359734026079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}