{"id":"W3196847619","doi":"10.1002/ejoc.202101059","title":"Ammonium Chloride‐Promoted Rapid Synthesis of Monosubstituted Ureas under Microwave Irradiation","year":2021,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Cyanate; Phosgene; Nucleophile; Urea; Organic chemistry; Chloride; Microwave chemistry; Ammonia; Organic synthesis; Microwave irradiation; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003813261,0.0001772046,0.0003225594,0.00002464508,0.00004134515,0.00002686304,0.000285469,0.00008494006,0.0005831106],"category_scores_gemma":[0.0006510401,0.0001668717,0.0003295795,0.0002097116,0.00007153044,0.000006924723,0.00009590508,0.0001693532,0.00000835339],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003501767,"about_ca_system_score_gemma":0.000161317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":8.894201e-7,"about_ca_topic_score_gemma":9.096007e-7,"domain_scores_codex":[0.9986385,0.0001144964,0.0006183367,0.0002442054,0.000208767,0.0001756601],"domain_scores_gemma":[0.9985788,0.00003704218,0.0005378632,0.0003489814,0.0003503182,0.0001470319],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001139397,0.0001314911,0.0001157961,0.00004178521,0.0003421722,0.00007977994,0.00001558064,0.00001508234,0.9951512,0.000001003723,0.0004558946,0.003536249],"study_design_scores_gemma":[0.0004045959,0.00002900277,0.00103446,0.00007156388,0.0001986885,0.000307828,0.0001007207,0.000008291905,0.993948,0.00001075707,0.00371691,0.0001691701],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936488,0.001541742,0.001258689,0.0003331112,0.00006946435,0.0000209993,0.00001140159,0.000005665321,0.003110074],"genre_scores_gemma":[0.9976555,0.0006005637,0.000689308,0.0000573884,0.0004826543,3.314819e-7,0.00003796406,0.00003850714,0.0004377659],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004006664,"threshold_uncertainty_score":0.6804832,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007258326640888955,"score_gpt":0.1942017022397533,"score_spread":0.1869433755988643,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}