{"id":"W3197293693","doi":"10.1021/acs.cgd.1c00791","title":"A Supramolecular [π-radical]<sub>2</sub> Unit Acts as a Ligand: Coordination of La and Ce by a Pancake-Bonded Pair","year":2021,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Supramolecular chemistry; Chemistry; Ligand (biochemistry); Lanthanide; Crystallography; Coordination sphere; Radical; Denticity; Coordination complex; Stereochemistry; Dimer; Crystal structure; Ion; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007663672,0.0002309507,0.0001792334,0.000097157,0.0001817261,0.0003536334,0.0003963788,0.0002864783,0.001680724],"category_scores_gemma":[0.0001000393,0.0001479603,0.0001012166,0.00008177657,0.0002235749,0.0003731443,0.0002799301,0.0002557322,0.0005709877],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002088562,"about_ca_system_score_gemma":0.0001443706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001255768,"about_ca_topic_score_gemma":0.0002040126,"domain_scores_codex":[0.9999498,0.000007551634,0.0000032802,0.00001585512,0.000009786352,0.00001366383],"domain_scores_gemma":[0.9999347,0.000008670402,0.00001551495,0.00001018134,0.000006016268,0.00002499276],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004098211,0.00001198001,0.0001440577,0.0000373481,0.000003746587,0.00005559345,0.00001889712,0.000153671,0.9962041,0.0004962092,0.00006975095,0.002763646],"study_design_scores_gemma":[0.00003509762,0.0003818439,0.001034376,0.000005344544,0.00001257859,0.0004005516,0.0000343918,0.002206979,0.9903145,0.000227886,0.005330538,0.00001582429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902073,0.0004369632,0.005833865,0.0001334025,0.00003079245,0.00003177509,0.00006019579,0.0002734691,0.002992288],"genre_scores_gemma":[0.9910813,0.000181287,0.005940422,0.00006866812,0.00001445539,0.00002598277,0.00007103583,0.00001695889,0.002599925],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001680724,"threshold_uncertainty_score":0.005622625,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01471868390171119,"score_gpt":0.2317447954204188,"score_spread":0.2170261115187076,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}