{"id":"W3199423131","doi":"10.1007/s12274-021-3857-2","title":"Rational design of palladium single-atoms and clusters supported on silicoaluminophosphate-31 by a photochemical route for chemoselective hydrodeoxygenation of vanillin","year":2021,"lang":"en","type":"article","venue":"Nano Research","topic":"Catalysis and Hydrodesulfurization Studies","field":"Engineering","cited_by":78,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Hydrodeoxygenation; Palladium; Catalysis; Photochemistry; Metal; Chemistry; Materials science; Organic chemistry; Selectivity","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004500181,0.0001028146,0.0002408052,0.000128063,0.00006581003,0.00002042231,0.00007199818,0.00008764844,0.00001963857],"category_scores_gemma":[0.0003809822,0.000105177,0.00005032642,0.000471115,0.00009781636,0.00005839242,0.00003724887,0.0001035613,0.000001452463],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001082985,"about_ca_system_score_gemma":0.00009404685,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007813661,"about_ca_topic_score_gemma":0.000005516638,"domain_scores_codex":[0.9987831,0.00004550974,0.0002920424,0.0002314288,0.0004322763,0.0002156901],"domain_scores_gemma":[0.9985602,0.0005740108,0.00004408649,0.0001370926,0.0006328088,0.000051815],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001161304,0.0001117253,0.0000888627,0.0001066707,0.0001204168,5.592764e-7,0.000367685,0.002914308,0.9899516,0.00007677086,0.005718825,0.000426444],"study_design_scores_gemma":[0.0006956126,0.0001110523,0.0001335008,0.00002791416,0.00001495337,0.000001116081,0.0001070067,0.06021066,0.9380152,0.0001383597,0.0004584011,0.00008626861],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835225,0.0008517957,0.01391423,0.0001324506,0.00004520966,0.0007211946,0.0001545182,0.00003158535,0.0006265686],"genre_scores_gemma":[0.9985642,0.0001461453,0.0006150124,0.00001148221,0.00002089068,0.0001039274,0.000215241,0.00002044127,0.0003027053],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05729635,"threshold_uncertainty_score":0.4288994,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05083693855223146,"score_gpt":0.3004781623934897,"score_spread":0.2496412238412582,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}