{"id":"W3200291514","doi":"10.1002/chem.202102926","title":"Efficient Near‐Infrared Electrochemiluminescence from Au<sub>18</sub> Nanoclusters","year":2021,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrochemiluminescence; Nanoclusters; Photoluminescence; Materials science; Nanotechnology; Infrared; Infrared spectroscopy; Optoelectronics; Chemistry; Electrode; Physics; Physical chemistry; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005265424,0.0002649243,0.0002587034,0.00001640105,0.0005781798,0.0005091684,0.0006592327,0.00005229186,0.00141949],"category_scores_gemma":[0.0002123533,0.0002543996,0.0001718683,0.000229549,0.0001625721,0.00007052423,0.0002423921,0.0003495321,0.0005075171],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001698846,"about_ca_system_score_gemma":0.0004128164,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002104984,"about_ca_topic_score_gemma":5.319179e-7,"domain_scores_codex":[0.9978088,0.0001781943,0.0005370165,0.0005345666,0.0003967581,0.0005446345],"domain_scores_gemma":[0.9984167,0.00008557367,0.0003041437,0.0006074848,0.0002162763,0.0003697709],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001879876,0.0001003275,0.00004015931,0.00002056295,0.00001347564,0.0002323564,0.0002397785,0.0001290158,0.993611,0.000001210761,0.004149721,0.001443642],"study_design_scores_gemma":[0.0004817959,0.00001020162,0.0003913088,0.0001298522,0.00003714549,0.0005054697,0.0001620881,0.001270137,0.9898062,0.00002042744,0.006890237,0.000295083],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874597,0.0003724629,0.003202623,0.0003431072,0.0002549794,0.00006226154,0.00003619681,0.00007806983,0.008190658],"genre_scores_gemma":[0.9946515,0.00003575625,0.003278393,0.0002379803,0.0007974377,0.000007075217,0.00002585764,0.0000543466,0.0009116317],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007279026,"threshold_uncertainty_score":0.9999908,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01121212090081367,"score_gpt":0.2072652348134016,"score_spread":0.196053113912588,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}